| 400628-81-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 400628-81-1
• 化学式: C₅₄H₄₄N₆O₅Zn
• 分子量: 922.371
• InChiKey: YIQTYHMFLNHMTI-XCNDMJHQSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  sodium hydroxide 、 以 not given 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  Syntheses and characterization of porphyrins and their zinc complexes appending a multi-dentate ligand

  摘要：

  Porphyrins with a multi-dentate ligand have been prepared by a covalent binding of nitrilotriacetic acid (NTA) to meso-mono (ortho- or para-aminophenyl)-triphenylporphyrin. The equilibrium between the porphyrins and Zn2+ has been analyzed by ultra violet-visible (UV-Vis) and H-1 NMR spectroscopies and the porphyrins are found to form complexes with porphyrin/zinc ratios of 1:1 and 1:2. The zinc complexes with the porphyrin/zinc ratios of 1:1 and 1:2 have been prepared and characterized by UV-Vis, infrared (IR) and H-1 NMR spectroscopies. An accelerated zinc incorporation reaction into the porphyrin appending NTA at its ortho-phenyl group is reported. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00630-2
• 作为产物：
  描述：

  、 zinc diacetate 以 二氯甲烷 为溶剂， 以97%的产率得到
  参考文献：
  名称：

  Syntheses and characterization of porphyrins and their zinc complexes appending a multi-dentate ligand

  摘要：

  Porphyrins with a multi-dentate ligand have been prepared by a covalent binding of nitrilotriacetic acid (NTA) to meso-mono (ortho- or para-aminophenyl)-triphenylporphyrin. The equilibrium between the porphyrins and Zn2+ has been analyzed by ultra violet-visible (UV-Vis) and H-1 NMR spectroscopies and the porphyrins are found to form complexes with porphyrin/zinc ratios of 1:1 and 1:2. The zinc complexes with the porphyrin/zinc ratios of 1:1 and 1:2 have been prepared and characterized by UV-Vis, infrared (IR) and H-1 NMR spectroscopies. An accelerated zinc incorporation reaction into the porphyrin appending NTA at its ortho-phenyl group is reported. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00630-2