2',5'-Di-n-hexyl-p-terphenyl-4,4''-dicarboxylic acid | 141768-07-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2',5'-Di-n-hexyl-p-terphenyl-4,4''-dicarboxylic acid
• 英文别名: 4-[4-(4-Carboxyphenyl)-2,5-dihexylphenyl]benzoic acid
• CAS: 141768-07-2
• 化学式: C₃₂H₃₈O₄
• 分子量: 486.651
• InChiKey: OPPJEAVDVQKIPI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.2
• 重原子数：
  36
• 可旋转键数：
  14
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2',5'-Di-n-hexyl-p-terphenyl-4,4''-dicarboxylic acid 在 氯化亚砜 作用下， 以 甲苯 为溶剂， 反应 24.0h， 生成 2',5'-Di-n-hexyl-p-terphenyl-4,4''-dicarboxylic dichloride
  参考文献：
  名称：

  Synthesis and Properties of Stiff-Chain Polyesters Based on the Terphenyl Moiety

  摘要：

  The synthesis and the characterization of rigid-rod polyesters 2 and 3 deriving from 2',5'-dihexyl-p-terphenyl-4,4''-diol 7 and from 2',5'-dihexyl-p-terphenyl-4,4''-dicarboxylic dichloride 8 together with a facile synthesis of monomers 7 and 8 is described. It is shown that these polyesters exhibit a very good solubility in common organic solvents. Therefore these materials present interesting model compounds for comprehensive studies of rigid-rod polymers in solution.

  DOI：

  10.1080/10587259408037772
• 作为产物：
  描述：

  4-溴苯甲酸乙酯 在 四(三苯基膦)钯 氢氧化钾 、 sodium carbonate 作用下， 以 乙醇 、 甲苯 为溶剂， 反应 72.0h， 生成 2',5'-Di-n-hexyl-p-terphenyl-4,4''-dicarboxylic acid
  参考文献：
  名称：

  Synthesis and Properties of Stiff-Chain Polyesters Based on the Terphenyl Moiety

  摘要：

  The synthesis and the characterization of rigid-rod polyesters 2 and 3 deriving from 2',5'-dihexyl-p-terphenyl-4,4''-diol 7 and from 2',5'-dihexyl-p-terphenyl-4,4''-dicarboxylic dichloride 8 together with a facile synthesis of monomers 7 and 8 is described. It is shown that these polyesters exhibit a very good solubility in common organic solvents. Therefore these materials present interesting model compounds for comprehensive studies of rigid-rod polymers in solution.

  DOI：

  10.1080/10587259408037772

文献信息

• Synthesis and Properties of Stiff-Chain Polyesters Based on the Terphenyl Moiety
  作者：U. Tiesler、T. Pulina、M. Rehahn、M. Ballauff

  DOI：10.1080/10587259408037772

  日期：1994.3

  The synthesis and the characterization of rigid-rod polyesters 2 and 3 deriving from 2',5'-dihexyl-p-terphenyl-4,4''-diol 7 and from 2',5'-dihexyl-p-terphenyl-4,4''-dicarboxylic dichloride 8 together with a facile synthesis of monomers 7 and 8 is described. It is shown that these polyesters exhibit a very good solubility in common organic solvents. Therefore these materials present interesting model compounds for comprehensive studies of rigid-rod polymers in solution.