(2-carboxy-2-oxo-ethyl)-dimethyl sulfonium ; bromide | 51033-97-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 酮酸及其衍生物
• 英文名称: (2-carboxy-2-oxo-ethyl)-dimethyl sulfonium ; bromide
• 英文别名: (2-Carboxy-2-oxo-aethyl)-dimethyl-sulfonium; Bromid
• CAS: 51033-97-7
• 化学式: Br*C₅H₉O₃S
• 分子量: 229.095
• InChiKey: VWEDPMLCELYKFG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.48
• 重原子数：
  10.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  54.37
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  二甲基硫 、 3-溴丙酮酸 在 硝基甲烷 作用下， 生成 (2-carboxy-2-oxo-ethyl)-dimethyl sulfonium ; bromide
  参考文献：
  名称：

  Notes - Conjugative Effect of Dimethylsulfonio Group in an Aliphatic System

  摘要：

  DOI：

  10.1021/jo01352a605

文献信息

• Laparoscopic Telescope with Alpha Port and Aesop to View Open Surgical Procedures
  作者：K. Mitchell Russell、Timothy J. Broderick、Eric J. DeMaria、Shanu N. Kothari、Ronald C. Merrell

  DOI：10.1089/109264201750539727

  日期：2001.8

  Laparoscopy has advanced surgery by allowing the surgeon to operate within a patient's abdominal and pelvic cavity with minimal trauma and scarring. The coupling of a video camera to the laparoscopic telescope has had the secondary effect of allowing others to view the surgical field either on color video monitors or by watching the video feed over the Internet at a remote location. These advancements have allowed better teaching and mentoring of operations. Open procedures can benefit from this technology as well but have suffered in the past from inadequate methods to depict the open surgical field. We used the Alpha Port and Aesop robot to position a sterile laparoscopic telescope near the surgical field to view open cholecystectomies performed on five pigs and to send the video feed over the Internet to remote physicians. Viewing the video on the monitor, the surgeons performed the operation in a comfortable ergonomic upright position. Both the surgeons and the remote physicians found the quality of the video to be excellent, and the remote physicians felt comfortable learning and mentoring surgical procedures using this technique.