3,3,3-Trichlor-1-nitropropan | 99968-87-3

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: 3,3,3-Trichlor-1-nitropropan
• 英文别名: 1,1,1-trichloro-3-nitro-propane；1,1,1-Trichlor-3-nitro-propan；1,1,1-Trichloro-3-nitropropane
• CAS: 99968-87-3
• 化学式: C₃H₄Cl₃NO₂
• 分子量: 192.429
• InChiKey: NNCAOGVANFMLII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3,3,3-trichloro-1-nitropropene 在 盐酸 、 tin(ll) chloride 作用下， 以 甲醇 为溶剂， 生成 3,3,3-Trichlor-1-nitropropan
  参考文献：
  名称：

  Dornow,A.; Mueller,A., Chemische Berichte, 1960, vol. 93, p. 32 - 40

  摘要：

  DOI：

文献信息

• Process for preparing high nitrile coatings on metal or plastic materials
  申请人：THE STANDARD OIL COMPANY

  公开号：EP0387437A1

  公开（公告）日：1990-09-19

  A process for producing a protective barrier coating comprises preparing a high nitrile latex composition, precipitating the high nitrile polymer from the high nitrile latex, dissolving the high nitrile polymer in a solvent to form a coating composition wherein the coating composition comprises a high nitrile polymer from about 5% to about 50% of the total coating composition and a solvent from about 50% to about 95% of the total coating composition, applying the high nitrile polymer coating composition onto a substrate, and drying the high nitrile polymer coating composition at temperatures from about room temperature to about 500°C to produce a tack free coating.

  一种生产保护性阻隔涂层的工艺包括制备高腈胶乳组合物，从高腈胶乳中析出高腈聚合物，将高腈聚合物溶解在溶剂中以形成涂层组合物，其中涂层组合物包括占涂层组合物总量约5%至约50%的高腈聚合物和占涂层组合物总量约50%至约95%的溶剂、将高腈聚合物涂层组合物涂在基材上，并在约室温至约 500°C 的温度下干燥高腈聚合物涂层组合物，以产生无粘性涂层。
• Process for polymerizing acrylonitrile
  申请人：Case Western Reserve University

  公开号：EP0872493A2

  公开（公告）日：1998-10-21

  This invention relates to a process for polymerising acrylonitrile, comprising: (A) forming a polymerisable mixture comprising acrylonitrile monomer, solvent and a metal catalyst; (B) contacting said mixture with an initiator, said initiator being selected from the group consisting of sulfonyl halides, halopropionitriles, substituted halopropionitriles in the form of monoadducts derived from sulfonyl halides and acrylonitrile, monoadducts derived from substituted sulfonyl halides and monomers other than acrylonitrile; or polymers containing end groups derived from sulfonyl halides, halopropionitriles, substituted halopropionitriles in the form of monoadducts derived from sulfonyl halides and acrylonitrile, or monoadducts derived from substituted sulfonyl halides and monomers other than acrylonitrile; and (C) polymerising said acrylonitrile monomer to form a polymer comprised of acrylonitrile. In one embodiment, the polymerisable mixture in step (A) further comprises at least one polymerisable comonomer other than acrylonitrile, and the polymer formed during step (C) is a copolymer or a multicomponent copolymer comprised of acrylonitrile and said at least one other polymerisable comonomer.

  本发明涉及一种聚合丙烯腈的工艺，包括(A) 形成由丙烯腈单体、溶剂和金属催化剂组成的可聚合混合物； (B) 将所述混合物与引发剂接触，所述引发剂选自以下组别：磺酰卤、卤丙酰腈、由磺酰卤和丙烯腈衍生的单体形式的取代卤丙酰腈、由取代磺酰卤和丙烯腈以外的单体衍生的单体；(C) 聚合所述丙烯腈单体以形成由丙烯腈组成的聚合物。在一个实施方案中，步骤(A)中的可聚合混合物还包括至少一种丙烯腈以外的可聚合共聚单体，而步骤(C)中形成的聚合物是由丙烯腈和所述至少一种其他可聚合共聚单体组成的共聚物或多组分共聚物。
• Nitroalkanes from Conjugated Nitroalkenes by Reduction with Complex Hydrides¹
  作者：H. Shechter、D. E. Ley、E. B. Roberson

  DOI：10.1021/ja01600a049

  日期：1956.10
• Inhibiting formation of foulants in acrylonitrile manufacture or recovery
  申请人：NALCO/EXXON ENERGY CHEMICALS, L.P.

  公开号：EP0872475B1

  公开（公告）日：2003-10-22
• US4837057A
  申请人：——

  公开号：US4837057A

  公开（公告）日：1989-06-06