[Cd(Me3N(+)CH2CO2(-))(NO3)]n(ClO4)n | 194477-67-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [Cd(Me3N(+)CH2CO2(-))(NO3)]n(ClO4)n
• CAS: 194477-67-3
• 化学式: C₅H₁₁NO₂*Cd*ClO₄*NO₃
• 分子量: 391.013
• InChiKey: JUQXVFYDUVSVFV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cadmium(II) nitrate tetrhydrate 、 sodium perchlorate 、 甜菜碱 以 水 为溶剂， 以58%的产率得到[Cd(Me3N(+)CH2CO2(-))(NO3)]n(ClO4)n
  参考文献：
  名称：

  Synthesis and crystal structures of two polymeric cadmium(II) complexes containing skew-skew carboxylato-bridges

  摘要：

  Two polymeric cadmium(II) complexes of betaine (Me3N+CH2CO2 = bet, [Cd-3(bet)(4)(H2O)(2) Cl-4](n)(ClO4)(2n) (1) and [Cd(bet)(2)(NO3)](n)(ClO4)(n) (2), have been prepared and characterized by X-ray single-crystal structural analysis. Complex 1 has the metal atoms in two coordination geometries. One is coordinated in a distorted octahedral geometry, being surrounded by one aqua ligand, two chloro ligands and three carboxylate oxygen atoms, while the other is also in a distorted octahedral geometry, bring surrounded by four chloro ligands and two carboxylate oxygen atoms. The aqua ligand acts as a terminal ligand [Cd-O = 2.368(2) Angstrom], whereas the chloro and carboxylate ligands bridge in the O,O' bridging modes [Cd-Cl = 2.5828(7), 2.6405(7); Cd-O = 2.251(2), 2.291(2) Angstrom] atom is six-coordinate in a distorted octahedral geometry. The nitrate anion binds in an isobidentate eta(2)-chelate mode [Cd-O = 2.405(3) Angstrom], while the carboxylate ligands bridge in the mu(2)-carboxylato-O,O' bridging mode [Cd-O = 2.225(2), 2.315(2) Angstrom]. The bet mu(2)-carboxylato-O,O' groups in complexes 1 and 2 exhibit unusual skew-skew bridging fashions, with a pair of metal atom located either on the same side or on the opposite side of the carboxylate plane. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00080-6