ammonium bis(2-phenylethyl)diselenophosphinate | 1238191-78-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ammonium bis(2-phenylethyl)diselenophosphinate
• 英文别名: azanium;bis(2-phenylethyl)-selanylidene-selenido-λ5-phosphane
• CAS: 1238191-78-0
• 化学式: C₁₆H₁₉PSe₂*H₃N
• 分子量: 417.251
• InChiKey: DTWUNCJBHGRWOP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.03
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  chromium chloride 、 ammonium bis(2-phenylethyl)diselenophosphinate 以 四氢呋喃 为溶剂， 反应 12.0h， 以83%的产率得到Cr[Se₂P(CH₂CH₂Ph)₂]₃
  参考文献：
  名称：

  Synthesis and comparative structural study of tris-chelated Sb(III), Bi(III) and Cr(III) diselenophosphinato complexes

  摘要：

  The tris-chelated Sb-III, Bi-III, and Cr-III complexes containing diselenophosphinate ligands, [(PhCH2CH2)(2) PSe2](-) and [Ph2PSe2](-), have been synthesized and fully characterized by X-ray crystallography, solution NMR (P-31, Se-77, and H-1), UV-Vis and ESI-mass techniques. X-ray diffraction analysis reveals that the M(Se2PR2)(3) (M = Sb, Bi and Cr) complexes are isostructural. In each of the compounds, the metal center is chelated by the three diselenophosphinate ligands in a distorted octahedral configuration. The M(Se2P)(3) fragment formed is similar to a three-bladed propeller. In Bi-III and Cr-III complexes, the R2PSe2- anions act as isobidentate ligands, whereas the anisobidentate nature of these anions in Sb-III complexes is observed. In the crystal packing of the complexes [except for Cr(Se2PPh2)(3)], there are supramolecular Se center dot center dot center dot Se interactions between adjacent molecules, which lead to a loosely connected dimer. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.10.005
• 作为产物：
  描述：

  bis(2-phenethyl)phosphine 在 selenium 、 氨 作用下， 以 乙醇 为溶剂， 反应 0.17h， 以96%的产率得到ammonium bis(2-phenylethyl)diselenophosphinate
  参考文献：
  名称：

  Facile Atom-Economic Synthesis of Ammonium Diselenophosphinates via Three-Component Reaction of Secondary Phosphines, Elemental Selenium, and Ammonia

  摘要：

  在温和条件下（EtOH-H2O，53-55摄氏度或EtOH，室温，10分钟），二取代次膦R2PH [R = Ph(CH2)2, PhCHMeCH2, PhCH2CHMe, 4-t-BuC6H4(CH2)2, 4-MeOC6H4(CH2)2, 2-furyl(CH2)2, 4-pyridyl(CH2)2, 6-Me-3-pyridyl(CH2)2, Ph]与元素硒和氨的三组分反应无需产生副产物，即可高效（高达96%）得到首批氨合二硒膦酸盐的代表。

  DOI：

  10.1055/s-0029-1218729

文献信息

• Atom-economic synthesis of ammonium diselenophosphinates from secondary phosphine selenides, elemental selenium, and ammonia
  作者：A. V. Artem’ev、N. K. Gusarova、S. F. Malysheva、A. A. Tatarinova、B. A. Trofimov

  DOI：10.1134/s1070363210070315

  日期：2010.7