cis-dichloro(2-(2'-amino-2'-methylpropoxy)-4,4-dimethyl-1,3,2-oxaaza-phospholidine-P,N)palladium(II) | 257930-04-4

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: cis-dichloro(2-(2'-amino-2'-methylpropoxy)-4,4-dimethyl-1,3,2-oxaaza-phospholidine-P,N)palladium(II)
• 英文别名: dichloropalladium;1-[(4,4-dimethyl-1,3,2-oxazaphospholidin-2-yl)oxy]-2-methylpropan-2-amine
• CAS: 257930-04-4
• 化学式: C₈H₁₉Cl₂N₂O₂PPd
• 分子量: 383.551
• InChiKey: LUHUHZJYVDCLEM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.74
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  56.5
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 3,3,8,8-tetramethyl-1,6-dioxa-4,9-diaza-5λ⁵-phosphaspiro[4.4]nonane 以 二氯甲烷 为溶剂， 以91%的产率得到cis-dichloro(2-(2'-amino-2'-methylpropoxy)-4,4-dimethyl-1,3,2-oxaaza-phospholidine-P,N)palladium(II)
  参考文献：
  名称：

  Platinum(II) and palladium(II) complexes with 3,3,8,8-tetramethyl-1,6-dioxa-4,9-diaza-5λ5-phosphaspiro[4,4]nonane

  摘要：

  Chelate metal complexes have been synthesised by reacting [MCODCl2] (M = Pd, Pt) and 3,3,8,8-tetramethyl-1,6-dioxa-4,9-diaza-5 lambda(5)-phosphaspiro[4,4]nonane. The general formula of the products is cis-[MCl2L], where L is a P,N-bidentate coordinated P(III) form of the initial hydrophosphorane. The structure of the products was determined by IR, H-1, C-13, N-14, N-15, P-31, and Pt-195 NMR spectroscopy, plasma and laser desorption mass spectrometry, sedimentation analysis, X-ray photoelectron spectroscopy and. in the case of platinum products, by single-crystal X-ray diffraction. A tendency of the complexes to reorganise in organic solvents was revealed. In the case of the palladium complex, the process is accompanied by an increase in the degree of nuclearity. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00348-5