[Pb(benzoate)(2,2'-bipyridine N,N'-dioxide)(NO3)]n | 1140207-78-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Pb(benzoate)(2,2'-bipyridine N,N'-dioxide)(NO3)]n
• CAS: 1140207-78-8；1140207-81-3
• 化学式: C₇H₅O₂*C₁₀H₈N₂O₂*NO₃*Pb
• 分子量: 578.506
• InChiKey: OWNLSISIAOZUTB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.05
• 重原子数：
  28.0
• 可旋转键数：
  2.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  160.21
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  sodium benzoate 、 lead(II) nitrate 、 N,N'-二氧化-2,2'-联吡啶 以 甲醇 为溶剂， 以65%的产率得到[Pb(benzoate)(2,2'-bipyridine N,N'-dioxide)(NO3)]n
  参考文献：
  名称：

  A mixed anionic lead(II) N-Oxide coordination polymer containing nitrato and benzoate ligands

  摘要：

  The structures of two forms of a mixed anionic one-dimensional coordination polymers of lead(II) nitrate derived from benzoate and 2,2'-bipyridyl N-oxide are reported. The X-ray crystal structures show subtle differences in the two binding modes of nitrate in the coordination polymers obtained from two independent solvents. The solid state UV-Vis spectra show differences in the absorption pattern of the crystalline solids obtained from different solvents. The solid state UV-Vis spectra as well as the solution spectra are compared. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.11.020