1-(tert-butyl)-2-isopropyl-3-methyl-5-methylenecyclopent-1-ene compound with tetraphenylmethane (1:1) | 123047-80-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1-(tert-butyl)-2-isopropyl-3-methyl-5-methylenecyclopent-1-ene compound with tetraphenylmethane (1:1)
• CAS: 123047-80-3
• 化学式: C₄H₇Cl₃N₃OPt*C₂₄H₂₀As
• 分子量: 797.902
• InChiKey: WWJLOYGLXFWSNX-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  肌酸酐 、 potassium tetrachloroplatinate(II) 、 四苯基鉮 以 水 为溶剂， 生成 1-(tert-butyl)-2-isopropyl-3-methyl-5-methylenecyclopent-1-ene compound with tetraphenylmethane (1:1)
  参考文献：
  名称：

  Absolute structure of a new paramagnetic platinum(II)-creatinine complex with a columnar structure

  摘要：

  A new platinum complex with creatinine [C3H2N2(O)(CH3)NH2] exhibiting paramagnetic properties was synthesized and fully characterized by crystallographic, spectral and magnetic measurements. The compound [AsPh4]+[Pt(creatinine)Cl3]- crystallizes to give a columnar honeycomb motif of tetraphenylarsonium cations with the channels occupied by creatinine anions. The shortest Pt-Pt distance is 7.622(1). A remarkable feature of the structure is the formation of short Pt ... H intermolecular bonds of 2.73(2) angstrom. The temperature dependence of both mu(eff) and EPR parameters of the complex has been studied.

  DOI：

  10.1016/s0277-5387(00)83183-6