Tridecansaeure-2-butylester | 55195-16-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Tridecansaeure-2-butylester
• 英文别名: Butan-2-yl tridecanoate
• CAS: 55195-16-9
• 化学式: C₁₇H₃₄O₂
• 分子量: 270.456
• InChiKey: ZJFXFNWDIZFEGF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  19
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  十三酰氯 、 仲丁醇 在 吡啶 作用下， 生成 Tridecansaeure-2-butylester
  参考文献：
  名称：

  Schlenk,W., Justus Liebigs Annalen der Chemie, 1973, p. 1179 - 1194

  摘要：

  DOI：

文献信息

• Manufacture of C13 higher fatty acids from their esters by carbonylation of dodecene-1 in ionic liquid medium
  作者：A. L. Lapidus、O. L. Eliseev、T. N. Bondarenko、N. H. Chau

  DOI：10.1134/s096554411006006x

  日期：2010.11

  The effect of catalyst nature, temperature, acidity, promoters, and feedstock composition on dodecene-1 carbonylation in the presence of Pd compounds in an ionic liquid medium yielding higher fatty acid and their esters was studied. Palladium salts without phosphine ligands show high activity in tetrabutylammonium bromide. In systems of this kind, the catalyst is suspended in the reaction mass in the form of Pd particles with a size of 4-10 nm. It was shown that the catalytic system can be repeatedly used without loss of activity. It is acceptable to use synthesis gas instead of bare carbon monoxide with the selectivity for tride-canoic acid increasing.