(tributyl-l5-phosphaneyl)(2,2,2-trifluoroacetoxy)silver | 554402-20-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (tributyl-l5-phosphaneyl)(2,2,2-trifluoroacetoxy)silver
• CAS: 554402-20-9
• 化学式: C₁₄H₂₇AgF₃O₂P
• 分子量: 423.204
• InChiKey: XDFLMEOXAJRIKA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三丁基膦 、 silver trifluoroacetate 以 乙醚 为溶剂， 以94%的产率得到(tributyl-l5-phosphaneyl)(2,2,2-trifluoroacetoxy)silver
  参考文献：
  名称：

  Phosphanstabilisierte Silber(I)–Carboxylate: Synthese und Verwendung in der Silber-CVD

  摘要：

  The synthesis of the silver(I)-carboxylate complexes [(R-3'P)(n)AgO2CR] (n = 1, R'= "Bu: 3a, R = CF3; 3b, R = C2F5; R' = C6H4CH2NMe2-2: 3c, R = CF3; 3d, R = C2F5; n = 2, R' = "Bu: 4a, R = CF3; 4b: R = C2F5) succeeds, when [AgO2CR] (1a, R = CF3; 1b, R = C2F5) is reacted with n equivalents of PR3'(2a, R'= "Bu; 2b, R'= C6CH2NMe2-2) (n = 1, 2); the yield amounts to 83-98%. Complexes 3 and 4 can be used for the deposition of silver on titaniumnitride-coated SiO2-wafers by the chemical vapour deposition (CVD) process, which could be shown by applying 4a as suitable precursor. REM studies show that closed silver layers were formed with a silver particle size between 50 and 100 nm. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)02166-6