3,3'-Dibrom-1,1'-biadamantan | 15417-11-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机溴化物
• 英文名称: 3,3'-Dibrom-1,1'-biadamantan
• 英文别名: 3,3'-Dibromo-1,1'-biadamantane；1-bromo-3-(3-bromo-1-adamantyl)adamantane
• CAS: 15417-11-5
• 化学式: C₂₀H₂₈Br₂
• 分子量: 428.25
• InChiKey: FSPYCPSJFWEANU-UHFFFAOYSA-N

物化性质

• 熔点：
  236-237 °C(Solv: 1,4-dioxane (123-91-1))
• 沸点：
  437.1±18.0 °C(Predicted)
• 密度：
  1.645±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  22
• 可旋转键数：
  1
• 环数：
  8.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3,3'-Dibrom-1,1'-biadamantan 在 氨 作用下， 生成 1,1'-联金刚烷-3,3'-二胺
  参考文献：
  名称：

  抗病毒药。2.与1-金刚烷胺有关的化合物的构效关系。

  摘要：

  DOI：

  10.1021/jm00288a019
• 作为产物：
  描述：

  1-溴金刚烷 在 溴 、 sodium 作用下， 以 正辛烷 为溶剂， 反应 8.0h， 生成 3,3'-Dibrom-1,1'-biadamantan
  参考文献：
  名称：

  基于1,1'-双金刚烷†的刚性核的合成

  摘要：

  已经开发了一种有效的策略来制备一系列基于1,1'-双金刚烷的刚性核。通过AlCl 3或AlBr 3的作用观察到溴苯在烷基化中的歧化。根据获得的结果，还概述了这些反应的拟议机制。

  DOI：

  10.1039/c5ra27528h

文献信息

• Ethynylphenylbiadamantane derivatives
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP2014636A1

  公开（公告）日：2009-01-14

  Disclosed is a halophenylbiadamantane derivative of following Formula (1): wherein R1, R2, R3, R4, R5, and R6 each independently represent, for example, a hydrogen atom or a halo-substituted or unsubstituted alkyl or cycloalkyl group having about six or less carbon atom(s), provided that at least one of R1 to R6 represents a substituent represented by following Formula (2): wherein X represents a halogen atom; and "n" denotes a natural number of 1 to 5, wherein when only one of R1 to R6 is a substituent of Formula (2), then at least one of R1 to R6 is a halo-substituted or unsubstituted alkyl or cycloalkyl group having about six or less carbon atom(s) or "n" is a natural number of 2 or more. The halophenylbiadamantane derivative is usable as an intermediate material for a wide variety of biadamantane derivatives.

  本发明揭示了以下式（1）的卤苯基双螺烷衍生物：其中R1、R2、R3、R4、R5和R6各自独立地代表例如氢原子或具有大约六个或更少碳原子的卤代或未卤代的烷基或环烷基基团，前提是R1到R6中至少有一个代表以下式（2）所表示的取代基：其中X代表卤素原子；“n”表示1到5的自然数，当R1到R6中仅有一个是式（2）的取代基时，那么R1到R6中至少有一个是具有大约六个或更少碳原子的卤代或未卤代的烷基或环烷基基团，或者“n”是2或更多的自然数。该卤苯基双螺烷衍生物可用作各种双螺烷衍生物的中间体材料。
• Synthesis of tetramers of 1,3-adamantane derivatives
  作者：Takashi Ishizone、Hiroyuki Tajima、Shinichi Matsuoka、Seiichi Nakahama

  DOI：10.1016/s0040-4039(01)01825-1

  日期：2001.12

  Novel tetramers of 1,3-adamantane and 5,7-dibutyl-1,3-adamantane were synthesized by the coupling reaction of 3-bromo-1,1′-biadamantane or 3-bromo-5,5′,7,7′-tetrabutyl-1,1′-biadamantane with sodium in n-octane or with magnesium in diethyl ether. Although the former 1,3-adamantane tetramer showed poor solubility in organic solvents, the latter tetrameric 5,7-dibutyl-1,3-adamantane was readily soluble

  通过3-溴-1,1'-双金刚烷或3-溴-5,5'，7,7的偶联反应合成了1,3-金刚烷和5,7-二丁基-1,3-金刚烷的新型四聚体'-四丁基-1,1'-双金刚烷，含正辛烷中的钠或含镁的二乙醚。尽管前者1,3-金刚烷四聚体在有机溶剂中的溶解度较差，但后者四元5,7-二丁基-1,3-金刚烷易溶于THF，氯仿和苯，并已通过NMR，IR，SEC和NMR进行了成功表征元素分析。
• Synthesis of rigid cores based on 1,1′-biadamantane
  作者：Xiangfeng Lai、Jianwei Guo、Shuqin Fu、Dongyu Zhu

  DOI：10.1039/c5ra27528h

  日期：——

  An efficient strategy has been developed for the preparation of a series of rigid cores based on 1,1′-biadamantane. Disproportionation of bromobenzene in the alkylation was observed through the effect of AlCl3 or AlBr3. Proposed mechanisms of these reactions have also been outlined on the basis of the results obtained.

  已经开发了一种有效的策略来制备一系列基于1,1'-双金刚烷的刚性核。通过AlCl 3或AlBr 3的作用观察到溴苯在烷基化中的歧化。根据获得的结果，还概述了这些反应的拟议机制。
• ORGANIC INSULATING MATERIALS, VARNISHES FOR ORGANIC INSULATING FILM EMPLOYING THEM, ORGANIC INSULATING FILMS AND SEMICONDUCTOR DEVICES
  申请人：MATSUTANI Mihoko

  公开号：US20090318610A1

  公开（公告）日：2009-12-24

  There are provided organic insulating materials exhibiting low permittivity, high heat resistance and high mechanical strength, as well as organic insulating films with low permittivity, high heat resistance and high mechanical strength that employ the same, and semiconductor devices comprising the foregoing. An organic insulating material comprising a compound represented by general formula (1), or a polymer obtained by polymerizing a compound represented by general formula (1), or a mixture of a compound represented by general formula (1) and the polymer. X-VW n Y  (1) (In formula (1), X and Y each independently represent one or more groups with polymerizable functional groups. V and W each represent a group having an adamantane or polyamantane structure, and they may be the same or different. The letter n represents an integer of 0 or greater).

  提供了有机绝缘材料，具有低介电常数、高耐热性和高机械强度，以及采用相同材料的低介电常数、高耐热性和高机械强度的有机绝缘膜，以及包括上述材料的半导体器件。有机绝缘材料包括由通式（1）表示的化合物、由通式（1）表示的化合物聚合得到的聚合物，或通式（1）表示的化合物和聚合物的混合物。X和Y各自独立表示具有可聚合功能基团的一个或多个基团。V和W分别表示具有金刚烷或聚金刚烷结构的基团，它们可以相同也可以不同。字母n表示大于等于0的整数。
• Benzoxazole Resin Precursor, Polybenzoxazole Resin, Resin Film And Semiconductor Device
  申请人：Enoki Takashi

  公开号：US20080206548A1

  公开（公告）日：2008-08-28

  A benzoxazole resin precursor comprising a first repeating unit which is obtained by the reaction of a bisaminophenol compound and a dicarboxylic acid compound, at least one of which has the diamondoid structure; a benzoxazole resin precursor further comprising a second repeating unit which is obtained by the reaction of a bisaminophenol compound having no diamondoid structure and a dicarboxylic acid compound having no diamondoid structure; a polybenzoxazole resin obtained by the ring-closing reaction with dehydration of the above benzoxazole resin precursor; a resin film constituted with the benzoxazole resin precursor or the polybenzoxazole resin. A polybenzoxazole resin and a resin film having excellent heat resistance and a small permittivity and a semiconductor device using the resin film can be obtained from the benzoxazole resin precursor.

  一种苯并噁唑树脂前体，包括第一重复单元，该单元由双氨基酚化合物和二羧酸化合物反应得到，其中至少一个具有金刚烷结构；一种苯并噁唑树脂前体，进一步包括第二重复单元，该单元由不具有金刚烷结构的双氨基酚化合物和不具有金刚烷结构的二羧酸化合物反应得到；通过上述苯并噁唑树脂前体的环合反应和脱水反应得到的聚苯并噁唑树脂；由苯并噁唑树脂前体或聚苯并噁唑树脂构成的树脂膜。可以从苯并噁唑树脂前体中获得具有优异耐热性和小介电常数的聚苯并噁唑树脂和树脂膜，以及使用树脂膜的半导体器件。