cis,trans-[Pt2(μ-I)(μ-PPh2)I2(PPh3)2] | 1429230-56-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis,trans-[Pt2(μ-I)(μ-PPh2)I2(PPh3)2]
• 英文别名: cis,cis-[Pt₂(μ-I)(μ-PPh₂)I₂(PPh₃)₂]
• CAS: 1429230-56-7；1429256-62-1
• 化学式: C₄₈H₄₀I₃P₃Pt₂
• 分子量: 1480.64
• InChiKey: RNGZWCITIYZIQL-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  0.48
• 重原子数：
  56.0
• 可旋转键数：
  10.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  [Pt2Cl(μ-PPh2)(PPh3)3](Pt-Pt) 以 四氢呋喃 、 丙酮 为溶剂， 反应 7.0h， 生成 cis,trans-[Pt2(μ-I)(μ-PPh2)I2(PPh3)2]
  参考文献：
  名称：

  Diplatinum complexes: Chemoselective reactions of the μ-orthometalated, metal–metal bonded complex [Pt2(μ-o-C6H4PPh2)(μ-PPh2)(PPh3)2] with acids. Crystal structures of [Pt2Cl(μ-PPh2)(PPh3)3], [Pt2I(μ-PPh2)(PPh3)3], [Pt2(μ-H)(μ-PPh2)I2(PPh3)2] and cis,cis-[Pt2(μ-I)(μ-PPh2)I2(PPh3)2]

  摘要：

  In order to investigate further the chemoselectivity of reactions involving the mu-orthometalated, metal-metal bonded dinuclear Pt(I) complex [Pt-2(mu-o-C6H4PPh2)(mu-PPh2)(mu-PPh3)(2)](Pt-Pt) (1), it was reacted with HCl and HI using various stoichiometries. The first step was the breaking of the metal-carbon bond and the formation of C-H and Pt-X bonds. When a 1:1 ratio was used, the complexes [Pt2X(mu-PPh2)(PPh3)(3)] (Pt-Pt) (2, X = Cl; 3, X = I) have been obtained but the use of a 2:1 ratio resulted instead in the formation of the complexes [Pt-2(mu-H)(mu-PPh2)X-2(PPh3)(2)](Pt-Pt) (4, X = Cl; 6, X = I). The latter transformed into [Pt-2(mu-X)(mu,-PPh2)X-2(PPh3)(2)] (5, X = Cl; 7, X = I) in the presence of an additional equivalent of HX. The cis,cis- and cis,trans-isomers of 7 were also obtained by oxidation of 3 with one equivalent of iodine. Whereas compounds 4, cis,cis-5, and cis,trans-7 have been characterized in solution, the complexes 2.1/2C(7)H(8), 3, 6 and cis,cis-7 have been isolated and structurally characterized by X-ray diffraction. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.08.030