potassium hexaphenoxotungstate(V) | 820213-47-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: potassium hexaphenoxotungstate(V)
• 英文别名: potassium hexaphenoxytungstate
• CAS: 820213-47-6
• 化学式: C₃₆H₃₀O₆W*K
• 分子量: 781.579
• InChiKey: XWHAOJILWOFIAX-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氢化钾 、 tungsten hexaphenoxide 在 C₆H₅OH 作用下， 以 四氢呋喃 为溶剂， 以64%的产率得到potassium hexaphenoxotungstate(V)
  参考文献：
  名称：

  六苯氧基钨酸盐（V）离子的合成；四乙铵和锂盐的X射线晶体结构

  摘要：

  金属锂，钠和钾与四氢呋喃中的六氧化钨（VI）相互作用会生成六苯基氧钨酸盐（V）离子[W（OPh）6 ] -的盐。冷冻的四氢呋喃中盐的电子顺磁共振光谱表明，对于Li +，Na +和K +盐，存在离子对，其在阳离子与苯氧基的氧原子之间相互作用。

  DOI：

  10.1016/s0277-5387(00)80861-x

文献信息

• Syntheses and electrochemistry of (p-XC6H4O)6W (1-X, X=H, CH3, OCH3, Cl, Br, OH, OCH2Ph) and (p-XC6H4O)5W(OC6H4OH) (X=H, CH3, OCH3, Cl, Br): an approach to electrocatalytic CH bond activation
  作者：Orson L. Sydora、Jonas I. Goldsmith、Thomas P. Vaid、Abigail E. Miller、Peter T. Wolczanski、Hector D. Abruña

  DOI：10.1016/j.poly.2004.08.006

  日期：2004.11

  Alcoholysis of W(OMe)(6) afforded (p-PhCH2OC6H4O)(6)W (1-OCH2Ph), which could be hydrogenated (10% Pd/C, 1 atm H-2) to prepare (p-HOC6H4O)(6)W (1-OH). Related alcoholyses of WCl6 with HOC6H4-p-X provided the hexaphenoxides (p-XC6H4O)(6)W (1-X, X = H, CH3, OCH3, Cl, Br) through minor modifications of literature procedures. Acid catalyzed treatment of 1-X with p-HOC6H4OCH2Ph provided a mixture of substitution products (p-XC6H4O)(6-x)W(OC6H4OCH2Ph), (x = 1, 5-X) that could be hydrogenated (10% Pd/C, 1 atm H-2) to a mixture of hydroxylated products. Chromatography permitted isolation of (p-XC6H4O)(5)W(OC6H4OH) (6-X, X = H, 19%; Me, 29%; OCH3, 19%; Cl, 12%; Br, 11%) in modest yields. Hexaphenoxides 1-X and 6-X manifested two electrochemical reduction waves whose positions were a function of para-substituent. When oxidized, 6-X and 1-OH were proposed to behave as W(V)quinone mimics, albeit at potentials capable of oxidizing hydrocarbons as shown via a thermochemical cycle. If the proposed transients (p-XC6H4O)(5)W(OC6H4O) (7-X) were generated, degradation was apparently competitive with CH bond activation. The structure of oligomeric K[(p-ClC6H4O)(6)W]}(infinity) (8-Cl) is addressed, and comments on the nature of radical CH bond activation in this and related systems are presented. (C) 2004 Elsevier Ltd. All rights reserved.