[Fe(2,6-bis(2-methylthiophenyliminomethyl)pyridine)(ClO4)2] | 1137443-39-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: [Fe(2,6-bis(2-methylthiophenyliminomethyl)pyridine)(ClO4)2]
• CAS: 1137443-39-0
• 化学式: C₂₁H₁₉Cl₂FeN₃O₈S₂
• 分子量: 632.282
• InChiKey: QKQSSVLWMPCRAI-UEJZETIGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Fe(2,6-bis(2-methylthiophenyliminomethyl)pyridine)(ClO4)2] 、 间氯过氧苯甲酸 以 乙腈 为溶剂， 生成 [Fe(IV)(2,6-bis(2-methylthiophenyliminomethyl)pyridine)(ClO4)(O)](1+)
  参考文献：
  名称：

  An iron(II) complex with a N3S2 thioether ligand in the generation of an iron(IV)-oxo complex and its reactivity in olefin epoxidation

  摘要：

  A new iron(II) complex bearing an N3S2 thioether ligand was synthesized and characterized with various spectroscopic techniques and X-ray crystallography. A mononuclear nonheme iron(IV)-oxo intermediate was generated in the reaction of the iron(II) complex with various terminal oxidants. Theiron (IV)-oxo species show a capability of epoxidizing olefins, and the olefin epoxidation occurs via an electrophilic oxidation mechanism. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.04.018
• 作为产物：
  描述：

  ferrous perchlorate 、 2,6-bis-[(2-methylthiophenyl)-2-azaethenyl]pyridine 以 乙腈 为溶剂， 以70%的产率得到[Fe(2,6-bis(2-methylthiophenyliminomethyl)pyridine)(ClO4)2]
  参考文献：
  名称：

  An iron(II) complex with a N3S2 thioether ligand in the generation of an iron(IV)-oxo complex and its reactivity in olefin epoxidation

  摘要：

  A new iron(II) complex bearing an N3S2 thioether ligand was synthesized and characterized with various spectroscopic techniques and X-ray crystallography. A mononuclear nonheme iron(IV)-oxo intermediate was generated in the reaction of the iron(II) complex with various terminal oxidants. Theiron (IV)-oxo species show a capability of epoxidizing olefins, and the olefin epoxidation occurs via an electrophilic oxidation mechanism. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.04.018