| 1417903-92-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• CAS: 1417903-92-4
• 化学式: C₂₆H₃₀N₆O₈
• 分子量: 554.56
• InChiKey: UAJLTORQXJHVFT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.91
• 重原子数：
  40.0
• 可旋转键数：
  20.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  187.04
• 氢给体数：
  0.0
• 氢受体数：
  10.0

反应信息

• 作为反应物：
  描述：

  、 在 copper(l) iodide 、 N,N-二异丙基乙胺 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以35%的产率得到
  参考文献：
  名称：

  Anthraquinone-modified calix[4]arene: click synthesis, selective calcium ion fluorescent chemosensor and INHIBIT logic gate

  摘要：

  Novel anthraquinone-modified calix[4] arene was synthesized by click chemistry and exhibited selective fluorescent enhancement in the presence of Ca2+, which is attributed to photo-induced electron-transfer effect from the 1,2,3-triazole ring. The enhanced fluorescence was further quenched by F- ion. Thus, the potential Ca2+ and F- ion switched INHIBIT logic gate has been constructed.

  DOI：

  10.1080/10610278.2012.656124
• 作为产物：
  描述：

  1,8-二羟基蒽醌 、 1-叠氮基-2-(2-(2-碘乙氧基)乙氧基)乙烷 在 caesium carbonate 作用下， 以 乙腈 为溶剂， 反应 36.0h， 以70%的产率得到
  参考文献：
  名称：

  Anthraquinone-modified calix[4]arene: click synthesis, selective calcium ion fluorescent chemosensor and INHIBIT logic gate

  摘要：

  Novel anthraquinone-modified calix[4] arene was synthesized by click chemistry and exhibited selective fluorescent enhancement in the presence of Ca2+, which is attributed to photo-induced electron-transfer effect from the 1,2,3-triazole ring. The enhanced fluorescence was further quenched by F- ion. Thus, the potential Ca2+ and F- ion switched INHIBIT logic gate has been constructed.

  DOI：

  10.1080/10610278.2012.656124