([(n-Bu)2Sn((2-pyrimidylthio)acetato)]2O)2 | 709614-30-2

• 英文名称: ([(n-Bu)2Sn((2-pyrimidylthio)acetato)]2O)2
• CAS: 709614-30-2；912561-84-3
• 化学式: C₅₆H₉₂N₈O₁₀S₄Sn₄
• 分子量: 1640.5
• InChiKey: BWXCTGOMTRLEJA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-嘧啶硫代乙酸 、 二正丁基氧化锡 以 苯 为溶剂， 以78%的产率得到([(n-Bu)2Sn((2-pyrimidylthio)acetato)]2O)2
  参考文献：
  名称：

  Synthesis, characterizations and crystal structures of di-n-butyltin(IV) complexes with heteroatomic (N, O or S) acid

  摘要：

  Two types of di-n-butyltin(IV) complexes {[(Bu2Sn)-Bu-n(O2CR)](2)O}(2) . L 1-4 and (Bu2Sn)-Bu-n(O2CR)(2)Y 5-8 (when L = H2O, R = 2-pyrazine 1; L = O, R = 2-pyrimidylthiomethylene 2, 1-naphthoxymethylene 3; L = C6H6, R = 2-naphthoxymethylene 4; when Y = H2O, R = 2-pyrazine 5; Y = O, R = 2-pyrimidylthiomethylene 6, 1-naphthoxymethylene 7, 2-naphthoxymethylene 8) have been prepared in 1: 1 or 1:2 molar ratios by reactions of di-n-butyltin oxide with the heteroatomic (N, O or S) carboxylic acids. The complexes 1-8 are characterized by elemental, IR, H-1 and C-13 NMR spectra. And except for complexes 6 and 7, the complexes 1-5 and 8 are also characterized by X-ray crystallography diffraction analyses, which reveal that the tin atom of complex 5 is seven-coordinated, while the complexes 1-4 and 8 are all hexa-coordinated. The nitrogen atom of the aromatic ring in complexes 1 and 5 participates in the interactions with the Sn atom. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.02.024