| 192117-80-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 192117-80-9
• 化学式: C₄₉H₃₈MnN₅S₂
• 分子量: 815.944
• InChiKey: YSHSDCIPOSDWTG-YKKPBKTHSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride 、 sodium N,N-diethyldithiocarbamate 以 甲醇 为溶剂， 以88%的产率得到
  参考文献：
  名称：

  Synthesis and spectroscopic studies of manganese porphyrin-thiolate complexes

  摘要：

  The synthesis and spectroscopic characterization of four manganese(III) porphyrin thiolates are reported. The investigated compounds are represented by (TPP)Mn(SR), where TPP is the dianion of tetraphenylporhyrin and R is C6H5, C6H4(p-NO2), Et2NCS and C4H8NCS. Each complex was characterized by UV-vis and H-1 NMR spectroscopy. The effects of axial ligands on the UV-vis spectra of synthesized manganese porphyrin complexes is discussed and proton isotropic shifts are shown to be predominantly contact in origin, reflecting extensive porphyrin-to-metal pi bonding. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00604-3