[(Mn(H2Cit)]n | 583844-43-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [(Mn(H2Cit)]n
• CAS: 583844-43-3
• 化学式: C₆H₅O₇*H*H₂O*Mn
• 分子量: 263.063
• InChiKey: FFIXAKPWAOATQM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -4.75
• 重原子数：
  15.0
• 可旋转键数：
  5.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  169.29
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  manganese(II)carbonate 、 一水柠檬酸 以 水 为溶剂， 以84%的产率得到[(Mn(H2Cit)]n
  参考文献：
  名称：

  Homo- and hetero-metallic manganese citrate complexes: Syntheses, crystal structures and magnetic properties

  摘要：

  A series of Mn citrate coordination polymers [NaMn(Hcit)](n) (1, H(4)Cit = citric acid), [MnCa2(Hcit)(2)(H2O)(4)](n) (2), [{Mn(Hcit)(H2O)(2)}(2)Mn(H2O)(4)](n) (3) and [{Mn(Hcit)(H2O)(2)}(2)Mn(H2O)(2)](n) (4) have been synthesized by the solvothermal method and the conventional solvent method. 1 and 2 represent novel examples of bimetallic Mn citrate complexes with 3-D architectures. In the structure of 1, Mn(mu-O)(3)Na and Mn(mu-O)(mu-OCO)Na units are alternately fused via edge-sharing to form Mn...Na...Mn chains and the citrate trianion links between the chains by terminal carboxylate groups. In the structure of 2 the Ca ions are correlated by carboxylate bridges to create a two-dimensional Ca-citrate layer at the a-c face and the Mn(II) ions form a helix chain along the a axis by carboxylate bridges. Each citrate trianion links 9 and 8 hetero-metal ions in 1 or 2, respectively, through component carboxylate and hydroxyl groups. In 3 and 4 both the Mn(Hcit)(H2O)(2) units are coupled to form centrosymmetrical dimer units, which construct the one-dimensional chain structure of 3 and the 3D network architecture of 4. Infrared spectra and the magnetic properties are also discussed, being associated with the bridging coordination mode of the carboxylate group. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.04.031

文献信息

• Carboxylate-rich hybrid ligands in Mn(<scp>ii</scp>) complexes as precursors for water oxidation reactions
  作者：C. R. Raymond Gan、Zhaolin Liu、Shi-Qiang Bai、Kian Soo Ong、T. S. Andy Hor

  DOI：10.1039/c3dt51666k

  日期：——

  A new family of MnII complexes stabilized by carboxylate-rich hybrid ligands has been synthesized, characterized and applied as catalytic precursors for MnO2 nanoparticles in water oxidation by (NH4)2Ce(NO3)6.

  我们合成并鉴定了富含羧基的混合配体所稳定的一系列新的 MnII 复合物，并将其用作 (NH4)2Ce(NO3)6 水氧化作用中 MnO2 纳米粒子的催化前体。
• JP2022/169401
  申请人：——

  公开号：——

  公开（公告）日：——