Ring opening reactions of [M(CO)3(η1-Ph2PCH2PPh2)(η2-Ph2PCH2PPh2)] M = Cr, Mo, or W with Rh or Ir complexes to give bimetallic systems: synthesis of [(OC)3Mo(µ-Ph2PNHPPh2)2RhCl(CO)]
摘要:
[(OC)3M(µ-Ph2PCH2PPh2)2Mâ²X(CO)]或[(OC)3M(µ-Ph2PCH2PPh2)2Mâ²(CO)2]+PF6â类型的配合物是通过标题中描述的方法或[Mâ²(CO)(δ-2-Ph2PCH2PPh2)2]Cl(Mâ²=Rh或Ir)与易失性Cr、Mo,或 W 的羰基衍生物发生开裂反应:描述了 Ph2PNHPPh2 的第一个双金属复合物。