mer-[RuCl₃(dppb)(H₂O)] | 243643-58-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: mer-[RuCl₃(dppb)(H₂O)]
• 英文别名: mer-[RuCl₃(1,4-bis(diphenylphosphine)butane)(H₂O)]；4-diphenylphosphanylbutyl(diphenyl)phosphane;trichlororuthenium;hydrate
• CAS: 243643-58-5
• 化学式: C₂₈H₃₀Cl₃OP₂Ru
• 分子量: 651.922
• InChiKey: DRIWJXMUHHIYPZ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  mer-[RuCl₃(dppb)(H₂O)] 、 氧化亚氮 以 二氯甲烷 为溶剂， 以85.3%的产率得到mer-RuCl3(NO)(1,4-bis(diphenylphosphino)butane)
  参考文献：
  名称：

  Synthesis and characterization of the mer-[RuCl3(NO)(dppb)] isomer. X-ray structures of fac-[RuCl3(NO)(dppm)], cis-[RuCl2(dppm)2] and mer-[RuCl3(NO)(dppb)] [dppm=1,2-Bis(diphenylphosphino)methane and dppb=1,4-Bis(diphenylphosphino)butane]

  摘要：

  The fac-[RuCl3(NO)(dppm)] (1) and cis-[RuCl2(dppm)(2)] (2) complexes were obtained with co-crystallization in the solid state from the reaction of RuCl3(NO) with the diphosphine in dichloromethane. mer-[RuCl3(NO)(dppb)] (3) was obtained from [RuCl3(dppb)(H2O)] by bubbling NO for 30 min in the same solvent. The crystal and molecular structures of these three compounds have been determined from X-ray studies. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00084-4
• 作为产物：
  描述：

  [RuCl2(1,4-bis(diphenylphosphino)butane)]2(μ-1,4-bis(diphenylphosphino)butane) 、 氯 生成 mer-[RuCl₃(dppb)(H₂O)]
  参考文献：
  名称：

  Synthesis and characterization of the mer-[RuCl3(NO)(dppb)] isomer. X-ray structures of fac-[RuCl3(NO)(dppm)], cis-[RuCl2(dppm)2] and mer-[RuCl3(NO)(dppb)] [dppm=1,2-Bis(diphenylphosphino)methane and dppb=1,4-Bis(diphenylphosphino)butane]

  摘要：

  The fac-[RuCl3(NO)(dppm)] (1) and cis-[RuCl2(dppm)(2)] (2) complexes were obtained with co-crystallization in the solid state from the reaction of RuCl3(NO) with the diphosphine in dichloromethane. mer-[RuCl3(NO)(dppb)] (3) was obtained from [RuCl3(dppb)(H2O)] by bubbling NO for 30 min in the same solvent. The crystal and molecular structures of these three compounds have been determined from X-ray studies. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00084-4

文献信息

• Ruthenium(II) complexes of 2-benzoylpyridine-derived thiosemicarbazones with cytotoxic activity against human tumor cell lines
  作者：Angelica E. Graminha、Cláudia Rodrigues、Alzir A. Batista、Letícia R. Teixeira、Elaine S. Fagundes、Heloisa Beraldo

  DOI：10.1016/j.saa.2007.06.005

  日期：2008.4

  Reaction of [RuCl3(dppb)H2O] (dppb = 1,4 bis(diphenylphospine)butane) with 2-benzoylpyridine thiosemicarbazone (H2Bz4DH) and its N(4)-methy) (H2Bz4M) and N(4)-phehyl (H2Bz4Ph) derivatives gave [RuCl(dppb)(H2Bz4DH)]Cl (1), [RuCl(dppb)(H2Bz4M)]Cl (2) and [RuCl(dppb)(H2Bz4Ph)]Cl (3). The cytotoxic activity of the studied compounds was tested against the MCF-7, TK-10 and UACC-62 human tumor cell lines. The precursor [RuCl3(dppb)H2O] exhibits cytocidal activity against the tree cell lines. H2BzDH, H2Bz4M, and [RuCl(dppb)(H2Bz4M)]Cl (2) show a selective cytocidal effect against the UACC-62 cell line which makes them the most promising compounds. (C) 2007 Elsevier B.V. All rights reserved.
• Electrosynthesis of binuclear ruthenium complexes from [RuCl3(dppb)(L)] precursors [L = pyridine, 4-methylpyridine or dimethyl sulfoxide; dppb = 1,4-bis(diphenylphosphino)butane]
  作者：Karen Wohnrath、Márcio Peres de Araujo、Luis Rogério Dinelli、Alzir Azevedo Batista、Icaro de Sousa Moreira、Eduardo Ernesto Castellano、Javier Ellena

  DOI：10.1039/b001422m

  日期：——

  Electrolysis has been examined as a method of synthesis for [(L)(dppb)Ru(μ-Cl)3RuCl(dppb)] complexes, where dppb = 1,4-bis(diphenylphosphino)butane and L = pyridine (py), 4-methylpyridine (4-pic) or dimethyl sulfoxide (DMSO), by using [RuCl3(dppb)(L)] as precursors. The products of the electrolysis were characterized by 31P-1H} NMR, cyclic voltammetry and near infrared spectroscopy. The presence of the [Ru2Cl5(dppb)2] complex in the electrochemical cell suggests a mechanism by which the starting original species from the bulk solution reacts with the reduced form [RuCl2(dppb)(L)] generated at the surface of the electrode. The crystal structure of the precursor mer-[RuCl3(dppb)(4-pic)] was determined by X-ray diffraction.