(2-(2,6-di-tert-butylanthracen-9-yl)-1H-imidazo[4,5-f][1,10] phenanthroline) | 1268621-96-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: (2-(2,6-di-tert-butylanthracen-9-yl)-1H-imidazo[4,5-f][1,10] phenanthroline)
• CAS: 1268621-96-0
• 化学式: C₃₅H₃₂N₄
• 分子量: 508.666
• InChiKey: LZNGHXXYAZOXOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.23
• 重原子数：
  39.0
• 可旋转键数：
  1.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  54.46
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  溴化氰 、 (2-(2,6-di-tert-butylanthracen-9-yl)-1H-imidazo[4,5-f][1,10] phenanthroline) 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 、 mineral oil 为溶剂， 反应 18.5h， 以67%的产率得到(2-(2,6-di-tert-butylanthracen-9-yl)-1H-imidazo[4,5-f][1,10]phenanthroline-1-carbonitrile)
  参考文献：
  名称：

  Blue light-emitting and electron-transporting materials based on dialkyl-functionlized anthracene imidazophenanthrolines

  摘要：

  Two novel blue light-emitting materials based on bis(tert-butyl)anthracenyl-imidazophenanthrolines (BAIPs) have been synthesized and extensively characterized. Both materials exhibited a non-aggregate feature with high fluorescent quantum efficiency and excellent thermal stability. They can serve both as emissive and electron-transporting materials used in electroluminescence (EL) device for blue emission with high luminescence and external quantum efficiency. This study demonstrates that they are potentially useful for a wide range of applications in EL technology. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.12.059
• 作为产物：
  描述：

  蒽 在 N-溴代丁二酰亚胺(NBS) 、 正丁基锂 、 ammonium acetate 、 溶剂黄146 、 三氟乙酸 作用下， 以 二氯甲烷 为溶剂， 反应 21.0h， 生成 (2-(2,6-di-tert-butylanthracen-9-yl)-1H-imidazo[4,5-f][1,10] phenanthroline)
  参考文献：
  名称：

  Blue light-emitting and electron-transporting materials based on dialkyl-functionlized anthracene imidazophenanthrolines

  摘要：

  Two novel blue light-emitting materials based on bis(tert-butyl)anthracenyl-imidazophenanthrolines (BAIPs) have been synthesized and extensively characterized. Both materials exhibited a non-aggregate feature with high fluorescent quantum efficiency and excellent thermal stability. They can serve both as emissive and electron-transporting materials used in electroluminescence (EL) device for blue emission with high luminescence and external quantum efficiency. This study demonstrates that they are potentially useful for a wide range of applications in EL technology. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.12.059