| 1018476-73-7

• CAS: 1018476-73-7
• 化学式: C₁₃H₁₉CoN₂O₃
• 分子量: 310.299
• InChiKey: PHLMRPQELHEDAY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2-环己烯-1-酮 、 在 lithium hexamethyldisilazane 作用下， 以 四氢呋喃 、 六甲基磷酰三胺 为溶剂， 以61%的产率得到
  参考文献：
  名称：

  Cobalt Dinitrosoalkane Complexes in the C−H Functionalization of Olefins

  摘要：

  The use of cobalt dinitrosoalkane complexes in the C-H functionalization of alkenes has been demonstrated. Reaction of a series of alkenes with Me(4)CpCo(CO)(2) in the presence of NO generates intermediate cobalt dinitrosoalkane complexes that can be deprotonated M to the nitrosyl group and added to various Michael acceptors. The resultant products can then undergo retrocycloaddition reactions in the presence of the original alkene to regenerate the starting cobalt dinitrosoalkane complex and release the functionalized alkene.

  DOI：

  10.1021/ja800738d
• 作为产物：
  描述：

  2,3-二氢呋喃 、 (Me4-cyclopentadienyl)Co(carbonyl)2 、 氧化亚氮 以 正己烷 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  Cobalt Dinitrosoalkane Complexes in the C−H Functionalization of Olefins

  摘要：

  The use of cobalt dinitrosoalkane complexes in the C-H functionalization of alkenes has been demonstrated. Reaction of a series of alkenes with Me(4)CpCo(CO)(2) in the presence of NO generates intermediate cobalt dinitrosoalkane complexes that can be deprotonated M to the nitrosyl group and added to various Michael acceptors. The resultant products can then undergo retrocycloaddition reactions in the presence of the original alkene to regenerate the starting cobalt dinitrosoalkane complex and release the functionalized alkene.

  DOI：

  10.1021/ja800738d