(9r,10r)-9,10-dimethyl-9,10-dihydroanthracene-9,10-diol | 17104-29-9

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: (9r,10r)-9,10-dimethyl-9,10-dihydroanthracene-9,10-diol
• 英文别名: 9r.10t-dimethyl-9.10-dihydro-anthracenediol-(9.10c)；9r.10t-Dimethyl-9.10-dihydro-anthracendiol-(9.10c)；trans-9,10-Dihydroxy-9,10-dimethyl-9,10-dihydro-anthracen；trans-9,10-Dimethyl-9,10-dihydro-9,10-dihydroxy-anthracen；trans-9,10-Dihydro-9,10-dihydroxy-9,10-dimethylanthracen
• CAS: 17104-29-9
• 化学式: C₁₆H₁₆O₂
• 分子量: 240.302
• InChiKey: VAJFPXIGVWUIHR-WKILWMFISA-N

物化性质

• 熔点：
  189-190 °C
• 沸点：
  420.4±40.0 °C(Predicted)
• 密度：
  1.220±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.51
• 重原子数：
  18.0
• 可旋转键数：
  0.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  40.46
• 氢给体数：
  2.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  (9r,10r)-9,10-dimethyl-9,10-dihydroanthracene-9,10-diol 在 盐酸 、 甲醇 、 苯 作用下， 生成 9,10-二甲基蒽
  参考文献：
  名称：

  THE SYNTHESIS OF 9,10-DIALKYLANTHRACENES

  摘要：

  DOI：

  10.1021/jo01217a008
• 作为产物：
  描述：

  甲基碘化镁 、 蒽醌 在 乙醚 、 苯 作用下， 生成 (9r,10r)-9,10-dimethyl-9,10-dihydroanthracene-9,10-diol 、 cis-9,10-dimethyl-9,10-dihydro-9,10-dihydroxyanthracene
  参考文献：
  名称：

  Lepage, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1959, vol. 248, p. 1193,1195

  摘要：

  DOI：

文献信息

• Pheromone content of azinphosmethyl-susceptible and -resistant obliquebanded leafrollers (Lepidoptera: Tortricidae) as a function of time of day and female age
  作者：Ashraf M. El-Sayed、R.M. Trimble

  DOI：10.4039/ent134331-3

  日期：2002.6

  The effect of time of day and age on the amounts and ratios of four pheromone compounds [(Z)-11-tetradecenyl acetate (Z11-14:Ac), (E)-11-tetradecenyl acetate (E11-14:Ac), (Z)-11-tetradecenol (Z11-14:OH), and (Z)-11-tetradecenal (Z11-14:Al)] was compared in azinphosmethyl-susceptible (susceptible) and -resistant (resistant) female obliquebanded leafrollers, Choristoneura rosaceana (Harris). The amounts of all four pheromone compounds varied during the hour before and five hours after the onset of scotophase. The glands of resistant females contained approximately one half the amount of Z11-14:Ac and Z11-14:OH as the glands of susceptible females during the second and third hours of scotophase, and between 50 and 70% as much Z11-14:Al as the glands of susceptible females during the hour before and second to fourth hours of scotophase. The glands of susceptible and resistant females contained similar amounts of E11-14:Ac. The relative amounts of each of the four pheromone compounds were affected by time of day but not by resistance status. There was a negative linear relationship between the amounts of each of the four compounds and female age in both types of females. The amounts of Z11-14:Ac and E11-14:Ac declined at similar rates with age in susceptible and resistant females; the amounts of Z11-14:OH and Z11-14:Al declined more rapidly with age in susceptible than in resistant females. The relative amounts of the four compounds were not affected by female age. Temporal variation in the relative amounts of pheromone in susceptible and resistant C. rosaceana may be associated with similar variation in the emission of pheromone and corresponding temporal variation in the relative attractiveness of the two types of females.

  摘要 比较了一天中的时间和年龄对四种信息素化合物[(Z)-11-十四烯基乙酸酯（Z11-14:Ac）、(E)-11-十四烯基乙酸酯（E11-14:Ac）、(Z)-11-十四烯醇（Z11-14：OH）和 (Z)-11-十四烯醛（Z11-14:Al）]进行了比较。所有四种信息素化合物的含量在光照开始前一小时和光照开始后五小时内各不相同。在光斑期的第二和第三小时，抗性雌虫腺体中 Z11-14:Ac 和 Z11-14:OH 的含量约为易感雌虫腺体的一半；在光斑期开始前一小时和第二至第四小时，抗性雌虫腺体中 Z11-14:Al 的含量约为易感雌虫腺体的 50% 至 70%。易感雌虫和抗性雌虫腺体中的 E11-14:Ac 含量相似。四种信息素化合物的相对含量受一天中时间的影响，但不受抗性状态的影响。两种雌虫的四种化合物的含量与雌虫的年龄呈负线性关系。在易感雌性和抗性雌性中，Z11-14:Ac和E11-14:Ac的含量随年龄下降的速度相似；在易感雌性中，Z11-14:OH和Z11-14:Al的含量随年龄下降的速度比抗性雌性快。四种化合物的相对含量不受雌性年龄的影响。易感性和抗性蔷薇雌虫信息素相对含量的时间变化可能与信息素释放量的相似变化以及两种雌虫相对吸引力的相应时间变化有关。
• Diels–Alder reactions of 9,10-anthraquinodimethane and 9-methyleneanthrone
  作者：Ian T. Millar、K. E. Richards

  DOI：10.1039/j39670000855

  日期：——

  The addition reactions of 9,10-anthraquinodimethane with maleic anhydride, dimethyl acetylenedicarboxylate, p-benzoquinone, and 1,4-naphthoquinone have been studied. Syntheses of benzo[a]pyrene, dibenzo[j,xyz]-heptaphene and some substituted and reduced derivatives of these hydrocarbons are reported, and the preparation of 1,4:11,14-dibenzo[h,rst]pentaphenediquinone. The reaction of 10-hydroxy-10-methylanthrone

  研究了9,10-蒽醌二甲烷与马来酸酐，乙炔二羧酸二甲酯，对苯醌和1,4-萘醌的加成反应。报道了苯并[ a ] py ，二苯并[ j，xyz ]-庚苯以及这些烃的一些取代和还原衍生物的合成，并制备了1,4：11,14-二苯并[ h，rst ]五苯二醌。研究了10-羟基-10-甲基蒽酮与乙炔二羧酸二甲酯和偶氮二羧酸二乙酯的反应。后者给出了新颖的7 H-二-苯并[ de，h ]邻苯二嗪体系。
• 474. Substituted anthracene derivatives. Part III. Further examples of 1 : 5-anionotropic rearrangements
  作者：G. M. Badger、R. S. Pearce

  DOI：10.1039/jr9500002314

  日期：——
• Lepage, Annales de Chimie (Cachan, France), 1959, vol. <13> 4, p. 1137,1176
  作者：Lepage

  DOI：——

  日期：——
• 118. Some isomeric amido- and amino-derivatives of 9-methyl- and 9,10-dimethyl-anthracene
  作者：A. H. Beckett、R. G. Lingard

  DOI：10.1039/jr9610000588

  日期：——