cyclotri(3-phenylbenzylideneamine-N,3'-diyl) | 1088651-46-0

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: cyclotri(3-phenylbenzylideneamine-N,3'-diyl)
• 英文别名: 7,19,31-Triazaheptacyclo[31.3.1.12,6.19,13.114,18.121,25.126,30]dotetraconta-1(36),2(42),3,5,7,9(41),10,12,14(40),15,17,19,21(39),22,24,26(38),27,29,31,33(37),34-henicosaene
• CAS: 1088651-46-0
• 化学式: C₃₉H₂₇N₃
• 分子量: 537.663
• InChiKey: BRZWUBIZQJOYKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  42
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3'-硝基-3-联苯甲醛 在 盐酸 、 铁粉 作用下， 以 乙醇 、 水 为溶剂， 反应 1.5h， 以61%的产率得到cyclotri(3-phenylbenzylideneamine-N,3'-diyl)
  参考文献：
  名称：

  Arylene Imine Macrocycles of C_3h and C₃ Symmetry from Reductive Imination of Nitroformylarenes

  摘要：

  Novel C-3-symmetric phenylene imine macrocycles have been synthesized by reductive imination of single nitroformylarenes. Pore size and geometric shape are dictated by the distance between and orientation of the nitro and aldehyde moieties in the precursor backbone. This reaction is facile, requires no purification of the products, and is environmentally friendly.

  DOI：

  10.1021/ol802302x

文献信息

• Arylene Imine Macrocycles of <i>C</i>_3h and <i>C</i>₃ Symmetry from Reductive Imination of Nitroformylarenes
  作者：Andrew L. Korich、Thomas S. Hughes

  DOI：10.1021/ol802302x

  日期：2008.12.4

  Novel C-3-symmetric phenylene imine macrocycles have been synthesized by reductive imination of single nitroformylarenes. Pore size and geometric shape are dictated by the distance between and orientation of the nitro and aldehyde moieties in the precursor backbone. This reaction is facile, requires no purification of the products, and is environmentally friendly.