Amorphous copolymers of tetrafluoroethylene and hexafluoropropylene
申请人:E.I. DU PONT DE NEMOURS & COMPANY INCORPORATED
公开号:EP1050546A2
公开(公告)日:2000-11-08
The invention provides a process for isolating tetrafluoroethylene polymer resin from aqueous dispersion produced by dispersion polymerization, comprising first freezing said dispersion to form frozen dispersion, then thawing said frozen dispersion to form thawed frozen dispersion, and then separating said resin from liquid of said thawed frozen dispersion.
Process for making vinyl fluoride interpolymers and dispersions thereof
申请人:——
公开号:US20020151665A1
公开(公告)日:2002-10-17
Interpolymers of 1-99 mol % vinyl fluoride and 99-1 mol % of at least one highly fluorinated monomer such as tetrafluoroethylene are disclosed. The interpolymers are characterized by the presence of ionic end groups and are prepared by polymerizing VF and fluorinated monomer in water with water-soluble free-radical initiators such as azoamidine initiators or persulfate initiators at temperatures within the range of 60 to 100° C. and reactor pressures within the range of 1 to 12 MPa (145 to 1760 psi). The invention further provides for protective self-supporting films and coatings formed from nonaqueous dispersions of the interpolymers, both for use on the surfaces of substrates including metal, plastic, ceramic, glass, concrete, fabric and wood.