(9E,12E)-9,12-Octadecadienamide | 3072-13-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (9E,12E)-9,12-Octadecadienamide
• 英文别名: (9E,12E)-octadeca-9,12-dienamide
• CAS: 3072-13-7
• 化学式: C₁₈H₃₃NO
• 分子量: 279.5
• InChiKey: SFIHQZFZMWZOJV-AVQMFFATSA-N

物化性质

• 熔点：
  51 °C
• 沸点：
  437.6±24.0 °C(Predicted)
• 密度：
  0.890±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  20
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.72
• 拓扑面积：
  43.1
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• Intercalates and exfoliates formed with long chain monomeric organic intercalant compounds having at least ten carbon atoms and composite materials containing same
  申请人：AMCOL INTERNATIONAL CORPORATION

  公开号：EP0846660A2

  公开（公告）日：1998-06-10

  Intercalates formed by contacting a layered material, e.g., a phyllosilicate, with an intercalant monomer including an alkyl radical having at least 10 carbon atoms to sorb or intercalate the intercalant monomer between adjacent platelets of the layered material. Sufficient intercalant monomer is sorbed between adjacent platelets to expand the adjacent platelets to a spacing of at least about 5 Å (as measured after water removal to a maximum of 5% by weight water), up to about 100 Å and preferably in the range of about 10-45 Å, so that the intercalate easily can be exfoliated into individual platelets. The intercalated complex can be combined with an organic liquid into a viscous carrier material, for delivery of the carrier material, or for delivery of an active compound; or the intercalated complex can be combined with a matrix polymer to form a strong, filled polymer matrix.

  将层状材料（如叶硅酸盐）与夹杂剂单体（包括具有至少 10 个碳原子的烷基）接触，使夹杂剂单体吸附或夹杂在层状材料的相邻小板之间而形成的夹杂物。在相邻小板之间吸附足够的插层单体，使相邻小板之间的间距扩大到至少约 5 Å（在除水至最大 5%（重量）水分后测量），最大约 100 Å，最好在约 10-45 Å 的范围内，这样插层单体就很容易剥离成单个小板。插层复合物可与有机液体结合成粘稠的载体材料，用于载体材料的输送或活性化合物的输送；或者插层复合物可与基质聚合物结合，形成坚固的填充聚合物基质。
• Intercalates formed by co-intercalation of monomer, oligomer or polymer intercalants and surface modifier intercalants and layered materials and nanocomposites prepared with the intercalates
  申请人：AMCOL INTERNATIONAL CORPORATION

  公开号：EP0846661A2

  公开（公告）日：1998-06-10

  The present invention discloses intercalates formed by contacting a layered material, e.g., a phyllosilicate, with an intercalant monomer surface modifier including an alkyl radical having at least 6 carbon atoms and a polymerizable monomer, oligomer or polymer. The intercalant monomer surface modifier converts the interlayer region of the layered materials from hydrophilic to hydrophobic, therefore, polymerizable monomers, oligomers or polymers can be easily intercalated into the interlayer spacing. The co-presence of the intercalant monomer surface modifier and polymerizable monomer, oligomer or polymer provide an environment for more polymerizable monomers, oligomers or polymers to be intercalated into the interlayer spacing and the intercalates are readily exfoliated into polymer matrices to form nanocomposites. The nanocomposites (e.g., epoxy-clay) prepared from the intercalates demonstrated enhanced mechanical, thermal and chemical resistance compared with pristine polymer matrices.

  本发明公开了通过将层状材料（如植硅酸盐）与插层单体表面改性剂（包括具有至少6个碳原子的烷基自由基和可聚合单体、低聚物或聚合物）接触而形成的插层材料。插层单体表面改性剂可将层状材料的层间区域从亲水性转化为疏水性，因此可聚合单体、低聚物或聚合物可以很容易地插层到层间距中。插层单体表面改性剂和可聚合单体、低聚物或聚合物的共存为更多的可聚合单体、低聚物或聚合物插层到层间距中提供了环境，插层物很容易剥离到聚合物基质中形成纳米复合材料。与原始聚合物基质相比，用插层材料制备的纳米复合材料（如环氧树脂-粘土）具有更强的机械性能、耐热性和耐化学性。
• Intercalates and exfoliates formed with functional monomeric organic compounds; composite materials containing same and methods of modifying rheology therewith
  申请人：AMCOL INTERNATIONAL CORPORATION

  公开号：EP0780340B1

  公开（公告）日：2002-03-20
• EP0846662A2
  申请人：——

  公开号：EP0846662A2

  公开（公告）日：1998-06-10
• ACTIVITY GENERATING DELIVERY MOLECULES
  申请人：Marina Biotech, Inc.

  公开号：EP2496260A1

  公开（公告）日：2012-09-12