[(2-diphenylphosphinoyl)ethyl]dibutylamine | 828936-13-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(2-diphenylphosphinoyl)ethyl]dibutylamine
• 英文别名: N-Butyl-N-[2-(diphenylphosphoryl)ethyl]butan-1-amine；N-butyl-N-(2-diphenylphosphorylethyl)butan-1-amine
• CAS: 828936-13-6
• 化学式: C₂₂H₃₂NOP
• 分子量: 357.476
• InChiKey: KWASHSXZFVJDFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  25
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二正丁胺 、 (乙烯基-苯基磷酰)苯 以 水 、 二甲基亚砜 为溶剂， 反应 4.0h， 以72%的产率得到[(2-diphenylphosphinoyl)ethyl]dibutylamine
  参考文献：
  名称：

  Synthesis and biological activity of dialkylamino-substituted phosphine oxides

  摘要：

  A series of dialkylamino-substituted phosphine oxides was synthesized and their physiological activity was studied.

  DOI：

  10.1134/s1070363212100052

文献信息

• Synthesis and Extractive Properties of Dialkylaminomethyl-substituted Dialkylamides of Diphenylphosphinoylacetic Acid
  作者：A. N. Yarkevich、A. N. Turanov、A. V. Kharitonov

  DOI：10.1007/s11176-005-0366-z

  日期：2005.7

  Dialkylamides of diphenylphosphinoylacetic acids, dialkylaminomethyl-substituted by the methylene group, were prepared by means of the Mannich reaction from diphenyl(dialkylcarbamoylmethyl)-phosphine oxides or by reaction of the latter compounds with tetraethylmethylenediamine. Extractive ability of the obtained compounds toward U(VI) and Pd(II) in nitrate media was studied.

  通过曼尼希反应从二苯基（二烷基氨基甲酰基甲基）膦氧化物制备了二苯基膦酰基乙酸的二烷基酰胺，或通过后者与四甲基二胺的反应制备了二烷基氨基甲酰基甲基被亚甲基取代的二苯基膦酰基乙酸的二烷基酰胺。研究了所获化合物在硝酸盐介质中对 U(VI) 和 Pd(II) 的萃取能力。