5-n-heptyloxy isophthaloylchloride | 131747-08-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-n-heptyloxy isophthaloylchloride
• 英文别名: 5-Heptoxybenzene-1,3-dicarbonyl chloride
• CAS: 131747-08-5
• 化学式: C₁₅H₁₈Cl₂O₃
• 分子量: 317.212
• InChiKey: WWENAVKUIYXFLB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  5-n-heptyloxy isophthaloylchloride 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 生成 1,3-bis<<<6-(1-propionylamino)pyrid-2-yl>amino>carbonyl>-5-(heptyloxy)benzene
  参考文献：
  名称：

  Transition-state stabilization and molecular recognition: acceleration of phosphoryl-transfer reactions by an artificial receptor

  摘要：

  An artificial receptor that is complementary to the proposed trigonal-bipyramidal intermediate for phosphoryl-transfer reactions has been designed. Kinetic measurements with P-31 NMR methods show that the receptor causes up to a 10-fold accleration in the aminolysis of phosphorodiamidic chloride derivatives, proceeding via an associative mechanism.

  DOI：

  10.1021/ja00182a017
• 作为产物：
  描述：

  5-(n-heptyloxy)isophthalic acid 在 氯化亚砜 作用下， 生成 5-n-heptyloxy isophthaloylchloride
  参考文献：
  名称：

  新型荧光酰胺基蒽蒽酚的合成，光物理和电化学性质†

  摘要：

  荧光amidoanthracenophanes 1，2，3和4是从不同的芳族二酰氯和通过简单的酰化氨基precyclophane获得。所有合成的amidoanthracenophanes 1，2，3和4示出了401和402，426和429，和之间的三个强的荧光条带在449至451纳米，并且表现出在循环伏安法两/三氧化还原峰，其是荧光性蒽的特性单位。

  DOI：

  10.1039/c5ra14357h

文献信息

• Liquid crystal display with alignment film of polyphenylenphthalamide-based material and method for fabricating the same
  申请人：——

  公开号：US20020182346A1

  公开（公告）日：2002-12-05

  An LCD and a method for fabricating the LCD includes a first substrate and a second substrate, a liquid crystal layer between the first substrate and the second substrate, and a coating of a polyphenylenephthalamide based material on at least one of the substrates, thereby providing an LCD having a reduced residual image, a strong anchoring energy, and a high thermal stability is achieved.

  一种液晶显示器和制造该液晶显示器的方法包括第一基板和第二基板、第一基板和第二基板之间的液晶层，以及在至少一个基板上的聚苯酞胺基材料涂层，从而提供了一种具有减少残像、强锚定能量和高热稳定性的液晶显示器。
• US7060332B2
  申请人：——

  公开号：US7060332B2

  公开（公告）日：2006-06-13
• Synthesis, photophysical and electrochemical properties of a new class of fluorescent amidoanthracenophanes
  作者：Ayyavoo Kannan、Perumal Rajakumar

  DOI：10.1039/c5ra14357h

  日期：——

  Fluorescent amidoanthracenophanes 1, 2, 3 and 4 were obtained from the various aromatic diacid chlorides and diamino precyclophane by simple acylation. All the synthesized amidoanthracenophanes 1, 2, 3 and 4 show three intense fluorescence bands between 401 and 402, 426 and 429, and at 449 to 451 nm, and exhibit two/three oxidation reduction peaks in the cyclic voltammetry which is characteristic of

  荧光amidoanthracenophanes 1，2，3和4是从不同的芳族二酰氯和通过简单的酰化氨基precyclophane获得。所有合成的amidoanthracenophanes 1，2，3和4示出了401和402，426和429，和之间的三个强的荧光条带在449至451纳米，并且表现出在循环伏安法两/三氧化还原峰，其是荧光性蒽的特性单位。
• Transition-state stabilization and molecular recognition: acceleration of phosphoryl-transfer reactions by an artificial receptor
  作者：Paolo Tecilla、Suk Kyu Chang、Andrew D. Hamilton

  DOI：10.1021/ja00182a017

  日期：1990.12

  An artificial receptor that is complementary to the proposed trigonal-bipyramidal intermediate for phosphoryl-transfer reactions has been designed. Kinetic measurements with P-31 NMR methods show that the receptor causes up to a 10-fold accleration in the aminolysis of phosphorodiamidic chloride derivatives, proceeding via an associative mechanism.