1.3.4-Trihydroxy-2-methyl-anthrachinon | 7485-42-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1.3.4-Trihydroxy-2-methyl-anthrachinon
• 英文别名: 1,3,4-Trihydroxy-2-methylanthraquinone；1,2,4-trihydroxy-3-methylanthracene-9,10-dione
• CAS: 7485-42-9
• 化学式: C₁₅H₁₀O₅
• 分子量: 270.241
• InChiKey: LLCRDJQKZPPODB-UHFFFAOYSA-N

物化性质

• 熔点：
  231-232 °C
• 沸点：
  537.6±45.0 °C(Predicted)
• 密度：
  1.583±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  94.8
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  吡啶 、 1.3.4-Trihydroxy-2-methyl-anthrachinon 、 乙酸酐 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Zahn; Ochwat, Justus Liebigs Annalen der Chemie, 1928, vol. 462, p. 88

  摘要：

  DOI：
• 作为产物：
  描述：

  2-(2,4,5-trimethoxy-3-methyl-benzoyl)-benzoic acid 在 硫酸 作用下， 生成 1.3.4-Trihydroxy-2-methyl-anthrachinon
  参考文献：
  名称：

  19.曲霉菌色素的化学性质。第一部分

  摘要：

  DOI：

  10.1039/jr9370000080

文献信息

• Mitter; Sen, Journal of the Indian Chemical Society, 1928, vol. 5, p. 637
  作者：Mitter、Sen

  DOI：——

  日期：——
• Mitter; Pal, Journal of the Indian Chemical Society, 1930, vol. 7, p. 259,261
  作者：Mitter、Pal

  DOI：——

  日期：——
• Eder; Manoukian, Helvetica Chimica Acta, 1926, vol. 9, p. 58
  作者：Eder、Manoukian

  DOI：——

  日期：——
• [EN] ANTICANCER ANTHRAQUINONES AND METHOD OF USE THEREOF<br/>[FR] ANTHRAQUINONES ANTICANCEREUX ET LEUR METHODE D'UTILISATION
  申请人：UNIV MICHIGAN STATE

  公开号：WO2003089576A2

  公开（公告）日：2003-10-30

  Anthraquinones are described which have anticancer or antitumor activity and which are useful for inhibiting cancer cells and cells comprising tumors in vitro or in vivo. Preferably, the anthraquinones have the chemical formula (1), wherein R1, is selected from the group consisting of to hydrogen, alkyl, and substituted alkyl; R2 is a group containing 1-12 carbons selected from the group consisting of alkyl, substituted alkyl, aldehyde, hydroxy, hydroxymethyl, acid group, carbohydrate and combinations thereof; and R3 is a group containing 1 to 12 carbons selected from the group consisting of methyl, alkyl, substituted alkyl, aldehyde, hydroxy, hydroxymethyl, acid group, carbohydrate, and combinations thereof. The preferred anthraquinones are 1-hydroxy-2-acetyl-3,6-methyl anthraquinone, 2­-acetyl-3,6-methyl anthraquinone monoacetate, 1­-hydroxy-2-acetyl-3,7-methyl anthraquinone, 2-acetyl-­3,7-methyl anthraquinone monoacetate, 1,2,8-­trihydroxy-3-methyl anthraquinone, 1,8-dihydroxy-2-0-­β-D-glucopyranoside anthraquinone, 1,2,8-trihydroxy-3-hydroxymethyl anthraquinone, and 1,8-dihydroxy-3-­carboxy anthraquinone.
• [EN] REDOX FLOW BATTERY ELECTROLYTES<br/>[FR] ÉLECTROLYTES DE BATTERIE À FLUX REDOX
  申请人：CMBLU PROJEKT AG

  公开号：WO2019158613A1

  公开（公告）日：2019-08-22

  The present invention relates to novel combinations of redox active compounds for use as redox flow battery electrolytes. The invention further provides kits comprising these combinations, redox flow batteries, and method using the combinations, kits and redox flow batteries of the invention.