2,3,5-tribromopyrrole | 77124-07-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 芳基卤化物
• 英文名称: 2,3,5-tribromopyrrole
• 英文别名: 1H-Pyrrole, 2,3,5-tribromo-；2,3,5-tribromo-1H-pyrrole
• CAS: 77124-07-3
• 化学式: C₄H₂Br₃N
• 分子量: 303.779
• InChiKey: MEPHPIGDGLIMFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  15.8
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  吡咯 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 四氢呋喃 为溶剂， 生成 2,3,5-tribromopyrrole
  参考文献：
  名称：

  Regioselective Syntheses of 2,3,4-Tribromopyrrole and 2,3,5-Tribromopyrrole

  摘要：

  2,3,4-Tribromopyrrole (1) and 2,3,5-tribromopyrrole (2) were each synthesized from pyrrole. Spectral data and antifeedant effects for synthetic 1 and the antipredatory chemical defense compound of the marine hemichordate Saccoglossus kowalevskii were in agreement, confirming the structure of the deterrent natural product as 1. Spectral data for 2 differed from synthetic and natural 1.

  DOI：

  10.1021/np0498399

文献信息

• Reduced graphene oxide grafted by the polymer of polybromopyrroles for nanocomposites with superior performance for supercapacitors
  作者：Shouzhi Wang、Ligang Gai、Haihui Jiang、Zhenzhen Guo、Nana Bai、Jianhua Zhou

  DOI：10.1039/c5ta06751k

  日期：——

  An integrated structure has been designed by grafting the polymer of polybromopyrroles (PPBP) onto reduced graphene oxide (RGO) to produce RGO/PPBP nanocomposites with superior electrochemical performance for supercapacitors.

  已经通过将聚合物聚溴吡咯烷（PPBP）嫁接到还原石墨烯氧化物（RGO）上设计了一种集成结构，以生产具有优越电化学性能的超级电容器RGO/PPBP纳米复合材料。
• Bromination and chlorination of pyrrole and some reactive 1-substituted pyrroles
  作者：H. M. Gilow、D. Edward Burton

  DOI：10.1021/jo00324a005

  日期：1981.5
• GILOW H. M.; BURTON D. E., J. ORG. CHEM., 1981, 46, NO 11, 2221-2225
  作者：GILOW H. M.、 BURTON D. E.

  DOI：——

  日期：——
• Regioselective Syntheses of 2,3,4-Tribromopyrrole and 2,3,5-Tribromopyrrole
  作者：Ejae A. John、Pamela Pollet、Leslie Gelbaum、Julia Kubanek

  DOI：10.1021/np0498399

  日期：2004.11.1

  2,3,4-Tribromopyrrole (1) and 2,3,5-tribromopyrrole (2) were each synthesized from pyrrole. Spectral data and antifeedant effects for synthetic 1 and the antipredatory chemical defense compound of the marine hemichordate Saccoglossus kowalevskii were in agreement, confirming the structure of the deterrent natural product as 1. Spectral data for 2 differed from synthetic and natural 1.