1-Phenyl-2-nitroethyl-p-bromphenylsulfon | 52265-15-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Phenyl-2-nitroethyl-p-bromphenylsulfon
• 英文别名: 1-Bromo-4-[(2-nitro-1-phenylethyl)sulfonyl]benzene；1-bromo-4-(2-nitro-1-phenylethyl)sulfonylbenzene
• CAS: 52265-15-3
• 化学式: C₁₄H₁₂BrNO₄S
• 分子量: 370.224
• InChiKey: COIYVZQJWNDNAZ-UHFFFAOYSA-N

物化性质

• 熔点：
  143 °C
• 沸点：
  542.7±50.0 °C(Predicted)
• 密度：
  1.554±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  88.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  反式硝基苯乙烯 、 (4-bromophenyl)diazonium chloride 在 二氧化硫 作用下， 以 溶剂黄146 、 丙酮 为溶剂， 以24%的产率得到1-Phenyl-2-nitroethyl-p-bromphenylsulfon
  参考文献：
  名称：

  Reaction of Arendiazonium Salts and SO₂with α-Nitroolefins

  摘要：

  In reaction of beta-nitrostyrene and 2-(2-nitrovinyl)furan with arenediazonium chlorides and SO2 in the presence of copper(H) chloride products were obtained resulting from addition of arylsulfonyl group and a hydrogen atom across the C=C bond: 2-nitro-1-phenylethylsulfonylarenes and 2-(1-aryisulfonyl-2-nitroethyl)furans respectively. An anion-radical mechanism of the reaction was suggested.

  DOI：

  10.1023/b:rujo.0000034940.16955.8e

文献信息

• Reaction of Arendiazonium Salts and SO₂with α-Nitroolefins
  作者：E. E. Bilaya、N. D. Obushak、A. M. Buchinskii、N. I. Ganushchak

  DOI：10.1023/b:rujo.0000034940.16955.8e

  日期：2004.2

  In reaction of beta-nitrostyrene and 2-(2-nitrovinyl)furan with arenediazonium chlorides and SO2 in the presence of copper(H) chloride products were obtained resulting from addition of arylsulfonyl group and a hydrogen atom across the C=C bond: 2-nitro-1-phenylethylsulfonylarenes and 2-(1-aryisulfonyl-2-nitroethyl)furans respectively. An anion-radical mechanism of the reaction was suggested.