1,2,4-tripropylbenzene | 41898-97-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2,4-tripropylbenzene
• 英文别名: 1,2,4-Tripropyl-benzol
• CAS: 41898-97-9
• 化学式: C₁₅H₂₄
• 分子量: 204.356
• InChiKey: NQLVMGZUKRNRQB-UHFFFAOYSA-N

物化性质

• 沸点：
  264 °C
• 密度：
  0.8622 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,2,4-tripropylbenzene 在 盐酸 、 三氯化铝 作用下， 生成 1,3,5-三正丙基苯
  参考文献：
  名称：

  The Action of Aluminum Chloride on Alkylbenzenes. V

  摘要：

  DOI：

  10.1021/ja01587a039
• 作为产物：
  描述：

  1,4-二丙基苯 在 二硫化碳 、 三氯化铝 、 copper oxide-chromium oxide 作用下， 生成 1,2,4-tripropylbenzene
  参考文献：
  名称：

  Wibaut; Paulis, Recueil des Travaux Chimiques des Pays-Bas, 1958, vol. 77, p. 792,798

  摘要：

  DOI：

文献信息

• Case Study of <i>N</i> ‐ ^<i>i</i> Pr versus <i>N</i> ‐Mes Substituted NHC Ligands in Nickel Chemistry: The Coordination and Cyclotrimerization of Alkynes at [Ni(NHC) ₂ ]
  作者：Lukas Tendera、Moritz Helm、Mirjam J. Krahfuss、Maximilian W. Kuntze‐Fechner、Udo Radius

  DOI：10.1002/chem.202103093

  日期：2021.12.20

  impact of two different NHC ligands in complexes [Ni(NHC)2] and the behavior of the complexes towards alkynes is presented. It demonstrates how small differences in the stereo-electronic features of closely related ligands can significantly alter the reactivity pattern. The reaction of (suitable precursors of) both complexes with alkynes gave η2-(C,C)-alkyne complexes [Ni(NHC)2](η2-alkyne)], although

  大与小：介绍了配合物 [Ni(NHC) 2 ] 中两种不同 NHC 配体的影响以及配合物对炔烃的行为。它展示了密切相关配体的立体电子特征的微小差异如何显着改变反应模式。两种配合物（合适的前体）与炔烃的反应得到η 2 -( C , C )-炔烃配合物 [Ni(NHC) 2 ]( η 2 -alkyne)]，尽管可用于 [Ni(Mes) 的配合物的数量2 Im) 2 ] 仅限于小炔烃和良好的受体炔烃。
• H-BPin/KO^<i>t</i>Bu Promoted Activation of Cobalt Salt to a Heterotopic Catalyst for Highly Selective Cyclotrimerization of Alkynes
  作者：Shuo Song、Chuhan Li、Tianfen Liu、Panke Zhang、Xiaoming Wang

  DOI：10.1021/acs.orglett.1c02493

  日期：2021.9.3
• Highly regioselective [2+2+2] cycloaddition of terminal alkynes catalyzed by titanium complexes of p-tert-butylthiacalix[4]arene
  作者：Naoya Morohashi、Katsuya Yokomakura、Tetsutaro Hattori、Sotaro Miyano

  DOI：10.1016/j.tetlet.2005.12.034

  日期：2006.2

  Mono- and dinuclear titanium complexes of p-tert-butylthiacalix[4]arene were applied as a catalyst for [2+2+2] cycloaddition of terminal alkynes. They showed high catalytic activity and regioselectivity toward 1,3,5-trisubstituted benzenes over 1,2,4-trisubstituted isomers. The regioselectivity was rationalized in terms of the steric effect of the thiacalixarene skeleton and the coordination of the bridging Sulfur atom to the titanium center. (c) 2005 Elsevier Ltd. All rights reserved.
• REPORT OF THE INTERNATIONAL CONSENSUS DEVELOPMENT CONFERENCE ON FEMALE SEXUAL DYSFUNCTION: DEFINITIONS AND CLASSIFICATIONS
  作者：ROSEMARY BASSON、JENNIFER BERMAN、ARTHUR BURNETT、LEONARD DEROGATIS、DAVID FERGUSON、JEAN FOURCROY、IRWIN GOLDSTEIN、ALESSANDRA GRAZIOTTIN、JULIA HEIMAN、ELLEN LAAN、SANDRA LEIBLUM、HARIN PADMA-NATHAN、RAYMOND ROSEN、KATHLEEN SEGRAVES、R. TAYLOR SEGRAVES、RIDWAN SHABSIGH、MARCALEE SIPSKI、GORM WAGNER、BEVERLY WHIPPLE

  DOI：10.1016/s0022-5347(05)67828-7

  日期：2000.3

  Purpose: Female sexual dysfunction is highly prevalent but not well defined or understood. We evaluated and revised existing definitions and classifications of female sexual dysfunction.Materials and Methods: An interdisciplinary consensus conference panel consisting of 19 experts in female sexual dysfunction selected from 5 countries was convened by the Sexual Function Health Council of the American Foundation for Urologic Disease. A modified Delphi method was used to develop consensus definitions and classifications, and build on the existing framework of the International Classification of Diseases-10 and DSM-TV: Diagnostic and Statistical Manual of Mental Disorders of the American Psychiatric Association, which were limited to consideration of psychiatric disorders.Results: Classifications were expanded to include psychogenic and organic causes of desire, arousal, orgasm and sexual pain disorders. An essential element of the new diagnostic system is the "personal distress" criterion. In particular, new definitions of sexual arousal and hypoactive sexual desire disorders were developed, and a new category of noncoital sexual pain disorder was added. In addition, a new subtyping system for clinical diagnosis was devised. Guidelines for clinical end points and outcomes were proposed, and important research goals and priorities were identified.Conclusions: We recommend use of the new female sexual dysfunction diagnostic and classification system based on physiological as well as psychological pathophysiologies, and a personal distress criterion for most diagnostic categories.
• Choi, Kyu Sang; Park, Moon Kyeu; Han, Byung Hee, Journal of Chemical Research, Miniprint, 1998, # 9, p. 2348 - 2362
  作者：Choi, Kyu Sang、Park, Moon Kyeu、Han, Byung Hee

  DOI：——

  日期：——