all-cis[2₃]metacyclophanetriene | 89822-57-1

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: all-cis[2₃]metacyclophanetriene
• 英文别名: (2Z,9Z,16Z)-tetracyclo[16.3.1.14,8.111,15]tetracosa-1(22),2,4(24),5,7,9,11,13,15(23),16,18,20-dodecaene
• CAS: 89822-57-1
• 化学式: C₂₄H₁₈
• 分子量: 306.407
• InChiKey: ZPIJHXNEQXDZFJ-OHWPVKQSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  24
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  all-cis[2₃]metacyclophanetriene 在 potassium tert-butylate 、 溴 作用下， 以 乙醚 、 氯仿 为溶剂， 反应 2.0h， 生成 [2.2.2]metacyclophane-1,9,17-triyne
  参考文献：
  名称：

  [2.2.2]Metacyclophane-1,9,17-triyne

  摘要：

  The titled strained cyclophane, the smallest member of this family to be known, was synthesized by bromination-dehydrobromination of the corresponding triene in good yield; its X-ray crystallographic analysis reveals an averaged sp bond angle of 158.6 degrees that is substantially bent from the normal, linear triple bond. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)01564-5
• 作为产物：
  描述：

  (3-bromobenzyl)(triphenyl)phosphonium bromide 在 正丁基锂 、 potassium tert-butylate 、 四氯化钛 、 锌 作用下， 以 乙二醇二甲醚 为溶剂， 反应 6.0h， 生成 all-cis[2₃]metacyclophanetriene
  参考文献：
  名称：

  [2.2.2]Metacyclophane-1,9,17-triyne

  摘要：

  The titled strained cyclophane, the smallest member of this family to be known, was synthesized by bromination-dehydrobromination of the corresponding triene in good yield; its X-ray crystallographic analysis reveals an averaged sp bond angle of 158.6 degrees that is substantially bent from the normal, linear triple bond. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)01564-5

文献信息

• Tanner, David; Wennerstroem, Olof, Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1983, vol. 37, # 8, p. 693 - 698
  作者：Tanner, David、Wennerstroem, Olof

  DOI：——

  日期：——
• [2.2.2]Metacyclophane-1,9,17-triyne
  作者：Takeshi Kawase、Noriko Ueda、Masaji Oda

  DOI：10.1016/s0040-4039(97)01564-5

  日期：1997.9

  The titled strained cyclophane, the smallest member of this family to be known, was synthesized by bromination-dehydrobromination of the corresponding triene in good yield; its X-ray crystallographic analysis reveals an averaged sp bond angle of 158.6 degrees that is substantially bent from the normal, linear triple bond. (C) 1997 Elsevier Science Ltd.