(E)-N,N'-diisopropylbenzimidamide

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-N,N'-diisopropylbenzimidamide
• 英文别名: (E)-N,N'-diisopropylbenzamidine；N,N'-di(propan-2-yl)benzenecarboximidamide
• 化学式: C₁₃H₂₀N₂
• 分子量: 204.315
• InChiKey: YFGXSEOSZBOLAD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  24.4
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (E)-N,N'-diisopropylbenzimidamide 、 正丁基锂 生成 lithium N,N’-diisopropyl-benzamidinate
  参考文献：
  名称：

  BRUNNER H.; WACHTER J., J. OF ORGANOMET. CHEM., 1979, 175 NO 2, 285-292

  摘要：

  DOI：
• 作为产物：
  描述：

  苯基锂 、 N,N'-二异丙基碳二亚胺 以 乙醚 、 二丁醚 为溶剂， 反应 2.0h， 以58%的产率得到(E)-N,N'-diisopropylbenzimidamide
  参考文献：
  名称：

  带有“倒置”嘧啶鎓甜菜碱作为芳基替代物的定制 Buchwald 型膦 - 与金的合成和配位化学 (I)

  摘要：

  公开了一种受 Buchwald 型膦启发的新配体支架。其设计包括用通过丙二酸亚基的 C-5 位置连接到邻膦基苯基部分的嘧啶甜菜碱正式取代原始原型的远端芳基。描述了该膦的生产合成途径及其与金 (I) 中心协调的能力。在固态下观察到金属中心和丙二酸基之间的弱键相互作用。

  DOI：

  10.1002/ejic.201403205

文献信息

• ORGANIC METAL COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE EMPLOYING THE SAME
  申请人：INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

  公开号：US20160164006A1

  公开（公告）日：2016-06-09

  Organic metal compounds and organic electroluminescence devices employing the same are provided. The organic metal compound has a chemical structure represented below: wherein R 1 , R 2 , R 3 , R 4 , and R 5 are independent and can be hydrogen, halogen, C 1-8 alkyl or C 1-8 alkoxy; L can be acetylacetone ligand, picolinic acid ligand, N,N′-diisopropylbenzamidinate, or N,N′-diisopropyl-diisopropyl-guanidinate.

  提供有机金属化合物和使用这种化合物的有机电致发光器件。有机金属化合物具有以下化学结构：其中R1、R2、R3、R4和R5是独立的，可以是氢、卤素、C1-8烷基或C1-8烷氧基；L可以是乙酰丙酮配体、吡啶甲酸配体、N,N'-二异丙基苯甲酰胺基体或N,N'-二异丙基-二异丙基胍基体。
• Radical and Nitrenoid Reactivity of 3-Halo-3-phenyldiazirines
  作者：Rafael Navrátil、Ján Tarábek、Igor Linhart、Tomáš Martinů

  DOI：10.1021/acs.orglett.6b01753

  日期：2016.8.5

  transfer from alkyllithiums (RLi) in THF-based solvent mixtures. The resulting 3-phenyldiazirinyl radical, observed by EPR spectroscopy, is eventually transformed to benzonitrile. In Et2O, 2 equiv of RLi add to both nitrogens of halodiazirine N═N bond, affording N,N′-dialkylbenzamidines. The nitrenoid reactivity of some N-alkyl-1H-diazirine intermediates is manifested by their insertion into the α-C–H bond

  3-卤代-3-苯基-3 H-二嗪（卤素= Br或Cl）在基于THF的溶剂混合物中从烷基锂（RLi）经历解离单电子转移。通过EPR光谱法观察到的所得3-苯基重氮基自由基最终转化为苄腈。在Et 2 O中，2个当量的RLi加到卤代二嗪基N═N键的两个氮原子上，得到N，N'-二烷基苯甲m 。某些N-烷基-1 H-二氮嗪中间体的类固醇反应性通过插入THF或Et 2 O的α-C–H键中来体现。
• [EN] METAL COMPLEX COMPRISING AMIDINE AND SUBSTITUTED CYCLOPENTADIENYL LIGANDS<br/>[FR] COMPLEXE MÉTALLIQUE COMPRENANT DE L'AMIDINE ET DES LIGANDS CYCLOPENTADIÉNYLE SUBSTITUÉS
  申请人：LANXESS ELASTOMERS BV

  公开号：WO2016041818A1

  公开（公告）日：2016-03-24

  A metal complex of the formula (1 ) CyLMZp(A)n (1 ), wherein M is a group 4 metal Z is an anionic ligand, p is number of 1 to 2, preferably 2, Cy is a cyclopentadienyl-type ligand substituted with at least one aliphatic C3-C20 hydrocarbyl group, which is bonded to the cyclopentadienyl-type ligand, in particular to its cyclopentadienyl ring, via a secondary, a tertiary or quaternary carbon atom and, L is an amidinate ligand of the formula (2), wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub1 is a substituent comprising a group 14 atom through which Sub1 is bonded to the imine carbon atom and Sub2 is a substituent comprising a heteroatom of group 15, through which Sub2 is bonded to the imine carbon atom and A is a neutral Lewis base ligand selected from the list consisting of ether, thioether, amine, tertiary phosphane, imine, nitrile and isonitrile,wherein the number of said metal ligands "n" is in the range of 0 to the amount that specifies the 18-electron rule.

  一种化学配合物的化学式（1）CyLMZp（A）n（1），其中M是4族金属，Z是一个阴离子配体，p是1至2的数字，最好是2，Cy是一种环戊二烯基类型的配体，其上至少有一个与环戊二烯基类型配体上的一个次生、三次或四次碳原子键合的脂肪烃基，L是一个化学式（2）的氨基酰配体，其中含有氨基的配体通过亚胺氮原子与金属M共价键合，Sub1是一个含有14族元素的取代基，通过Sub1与亲胺碳原子键合，Sub2是一个含有15族元素的取代基，通过Sub2与亲胺碳原子键合，A是从醚、硫醚、胺、三级膦、亚胺、腈和异腈的列表中选择的中性路易斯碱配体，其中金属配体“n”的数量在0到符合18电子规则的数量范围内。
• ORGANIC METAL COMPOUND AND ORGANIC LIGHT-EMITTING DEVICES EMPLOYING THE SAME
  申请人：INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

  公开号：US20190207127A1

  公开（公告）日：2019-07-04

  Organic metal compounds and organic light-emitting devices employing the same are provided. The organic metal compound has a chemical structure of Formula (I) or Formula (II): wherein X is O or S; L is R 12 is and, n is 0, 1, or 2.

  本发明提供有机金属化合物和使用相同的有机发光器件。该有机金属化合物具有化学结构式（I）或式（II）：其中X为O或S；L为R12；R12为和，n为0、1或2。
• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。