2-Ammonio-10-(methylsulfanyl)decanoate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-Ammonio-10-(methylsulfanyl)decanoate
• 英文别名: 2-azaniumyl-10-methylsulfanyldecanoate
• 化学式: C11H23NO2S
• 分子量: 233.37
• InChiKey: XVGBKWQWYRNGDG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  15
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  93.1
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• Biosynthetic Engineering of Glucosinolates
  申请人：Geu-Flores Fernando

  公开号：US20110016582A1

  公开（公告）日：2011-01-20

  The invention provides methods and materials, such as newly characterised genes, and novel processes, for converting a host from a phenotype whereby the host is unable to carry out glucosinolate (GSL) biosynthesis or chain elongation from an amino acid GSL-precursor to a phenotype whereby the host carries out said biosynthesis or elongation.

  本发明提供了一种将宿主从无法进行葡萄糖硫酸盐（GSL）生物合成或链延伸的表型转化为能够进行上述生物合成或延伸的表型的方法和材料，例如新鉴定的基因和新型工艺。
• P450 Monooxygenases of the cyp79 family
  申请人：——

  公开号：US20030166202A1

  公开（公告）日：2003-09-04

  The invention provides DNA coding for cytochrome P450 monooxygenases of the CYP79 family catalyzing the conversion of an aliphatic or aromatic amino acid or chain-elongated methionine homologue to the corresponding oxime. Preferred embodiments of the invention are enzymes catalyzing the conversion of L-Valine and L-Isoleucine such as the cassava enzymes CYP79D1 and CYP79D2, enzymes catalyzing the conversion of tyrosine such as the Triglochin maritima enzymes CYP79E1 and CYP79E2, enzymes catalyzing the conversion of tryptophan to the corresponding oxime indole-3-acetaldoxime such as the Arabidopsis thaliana enzyme CYP79A2 and the Brassica napus enzyme CYP79B5, and enzymes catalyzing the conversion of a chain-elongated methionine homologue such as the Arabidopsis thaliana enzymes CYP79F1 and CYP79F2. Transgenic expression of said DNA or parts thereof in plants can be used to manipulate the biosynthesis of corresponding glucosinolates or cyanogenic glucosides.

  该发明提供了编码CYP79家族细胞色素P450单加氧酶的DNA，其催化将脂肪族或芳香族氨基酸或链延长的蛋氨酸同源物转化为相应的肟类。该发明的优选实施例是催化L-缬氨酸和L-异亮氨酸转化的酶，例如木薯酶CYP79D1和CYP79D2，催化酪氨酸转化的Triglochin maritima酶CYP79E1和CYP79E2，催化色氨酸转化为相应的肟类吲哚-3-乙醛肟的Arabidopsis thaliana酶CYP79A2和Brassica napus酶CYP79B5，以及催化链延长的蛋氨酸同源物转化的Arabidopsis thaliana酶CYP79F1和CYP79F2。在植物中转基因表达该DNA或其部分可以用于操纵相应的硫代葡萄糖苷或氰基葡萄糖苷的生物合成。
• P450 MONOOXYGENASES OF THE CYP79 FAMILY
  申请人：Syngenta Participations AG

  公开号：EP1246906A2

  公开（公告）日：2002-10-09
• BIOSYNTHETIC ENGINEERING OF GLUCOSINOLATES
  申请人：University of Copenhagen

  公开号：EP2257630A2

  公开（公告）日：2010-12-08
• MODULATION OF ORAL MICROBIOTA
  申请人：Mars Incorporated

  公开号：EP3979813A1

  公开（公告）日：2022-04-13