9-fluorenylpotassium | 7307-10-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9-fluorenylpotassium
• 英文别名: potassium fluorenide
• CAS: 7307-10-0
• 化学式: C₁₃H₉K
• 分子量: 204.313
• InChiKey: ZPTVWSIHNPXKKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.89
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  9-fluorenylpotassium 、 三氯化铈 以 四氢呋喃 为溶剂， 生成 trifluorenylcerium
  参考文献：
  名称：

  Sharma, R. K.; Sharma, C. P., Journal of the Indian Chemical Society, 1987, vol. 64, p. 506 - 507

  摘要：

  DOI：
• 作为产物：
  描述：

  potassium;9H-fluoren-9-yl(phenyl)methanolate 生成 9-fluorenylpotassium
  参考文献：
  名称：

  BELETSKAYA, I. P.;SOLOVYANOV, A. A.;KARPYUK, A. D.;KUCHERYAVENKO, O. P.;R+, ZH. ORGAN. XIMII, 1982, 18, N 7, 1355-1361

  摘要：

  DOI：
• 作为试剂：
  描述：

  2-氟-1,3,5-三硝基-苯 在 9-fluorenylpotassium 作用下， 以 四氢呋喃 为溶剂， 以48%的产率得到potassium picrate
  参考文献：
  名称：

  Artamkina, G. A.; Egorov, M. P.; Beletskaya, I. P., Journal of Organic Chemistry USSR (English Translation), 1984, p. 1649 - 1659

  摘要：

  DOI：

文献信息

• Fluorenyl andansa-Dimethylsilylbis(fluorenyl) Derivatives of Divalent Ytterbium and Samarium − Synthesis and Structure of the First Mixed-Ligand LnII Classic Sandwich Complex (C13H9)(C5Me5)Yb(DME)
  作者：Alexander A. Trifonov、Evgenii N. Kirillov、Sebastian Dechert、Herbert Schumann、Mikhail N. Bochkarev

  DOI：10.1002/1099-0682(200109)2001:10<2509::aid-ejic2509>3.0.co;2-f

  日期：2001.9

  (C13H9)YbI(DME) (5), but the redistribution products YbI2(DME) and 2. The first mixed-ligand sandwich complex of a divalent lanthanide metal (C13H9)(C5Me5)Yb(DME) (6) was prepared in a one-pot reaction of 4 with C5Me5H and C13H9K in DME. ansa-Me2Si(C13H8)2Yb(THF) (7) and ansa-Me2Si(C13H8)2Sm(THF)4 (8) were obtained by treatment of the appropriate LnII iodides with ansa-Me2Si(C13H9)2K2 in THF. The molecular

  二价镱 (C13H9)2Yb(L)n 的新型芴基配合物 [L = THF, n = 2 (1); L = DME, n = 1 (2)] 已通过 YbI2(THF)2 与 2 当量的反应制备。 K 以及 (C10H8)Yb(THF)2 与芴在 THF 中的反应。tBuN=CHCH=NtBu (DAD) 对 1 的氧化导致 ( )2Yb(DAD) (3) 的形成。YbI(DME)2]2(μ- )} (4) 与芴的反应没有得到 ( )YbI(DME) (5)，而是重新分配产物 YbI2(DME) 和 2。第一个混合二价镧系元素金属 ( )(C5Me5)Yb(DME) (6) 的配体夹心络合物是在 4 与 C5Me5H 和 K 在 DME 中的一锅反应中制备的。ansa-Me2Si(C13H8)2Yb(THF) (7) 和 ansa-Me2Si( )2Sm(THF)4
• η3-Allyl complexes of molybdenum—IV. Preparation and crystal structures of some substituted-cyclopentadienyl molybdenum allyl derivatives
  作者：O. Andell、R. Goddard、S. Holle、P.W. Jolly、C. Krüger、Y.H. Tsay

  DOI：10.1016/s0277-5387(00)86504-3

  日期：1989.1

  Abstract A series of substituted-cyclopentadienyl molybdenum allyl derivatives has been prepared by reacting (η 3 -C 3 H 5 ) 3 MoCl with substituted-cyclopentadienyl and -indenyl alkali metal salts. In general, the isolated products are of the type Cp′Mo(η 3 -C 3 H 5 ) 2 and in three cases this has been confirmed by crystal structure determinations. Spectroscopic evidence suggests that at low temperatures

  摘要通过使（η3 -C 3 H 5）3 MoCl与取代的环戊二烯基和-茚基碱金属盐反应，制备了一系列的取代环戊二烯基钼烯丙基衍生物。通常，分离出的产物为Cp'Mo（η3 -C 3 H 5）2类型，这在三种情况下已通过晶体结构测定得到证实。光谱证据表明，在低温下还形成了具有Cp'Mo（η3 -C 3 H 5）2（η1 -C 3 H 5）组成的化合物。与芴基钾的反应是反常的：NMR光谱和晶体结构确定表明，产物（η3-芴基）Mo（η3 -C 3 H 5）3包含四个与金属不对称键合的η3-烯丙基原子。
• Phenylation of cyclic and acyclic pentadienyl carbanions by π-fluorobenzenetricarbonylchromium
  作者：Alberto Ceccon、Alessandro Gambaro、Francesca Gottardi、Francesco Manoli、Alfonso Venzo

  DOI：10.1016/0022-328x(89)88043-x

  日期：1989.3

  and 1,1′,5,5′-tetramethyl-1,3-pentadienyl carbanions by π-fluorobenzenetricarbonylchromium in ethereal solvents at 0°C gives good yields (> 70%) of complexes in which the phenyl-Cr(CO)3 group is σ-bonded to a pentadienyl skeleton. The regio and stereo isomers obtained have been identified by accurate 1H NMR study. Monotoring of the reaction by IR spectroscopy has shown that the mechanism of substitution

  环戊二烯基，茚基，芴基，1,3-戊二烯基，2,4-二甲基-1,3-戊二烯基和1,1'，5,5'-四甲基-1,3-戊二烯基碳负离子通过π-氟苯三羰基铬的苯甲酰化醚溶剂在0°C时可获得良好的收率（> 70％），其中苯基-Cr（CO）3基团通过σ-键键合到戊二烯基骨架上。通过精确的1 H NMR研究已鉴定出所获得的区域和立体异构体。通过IR光谱对反应的单分子化表明，用环状阴离子取代氟的机理与用无环阴离子取代氟的机理不同。
• Systematic Ranking of Nucleophiles as Electron Donors.
  作者：Kim Daasbjerg、Stig R. Knudsen、Katrine N. Sonnichsen、Adalgisa R. Andrade、Steen U. Pedersen、Hiroaki Murase、Tatsuya Shono、H. Toftlund

  DOI：10.3891/acta.chem.scand.53-0938

  日期：——

  A systematic ranking of different nucleophiles (including enolates, phenolates, thiophenolates, hydroxide, cyanide) with respect to their ability to stabilise the transition state of substitution reactions has been carried out in acetonitrile and dimethyl sulfoxide. The method is based on a comparison of the rate constant, k(SUB), for the substitution reaction between a given nucleophile and benzyl chloride with the rate constant, ka(ET), for the corresponding electron transfer from an aromatic radical anion to benzyl chloride. The ratio k(SUB)/k(ET) expresses the rate enhancement due to electronic interaction in the transition state, Delta G(sta), of the substitution reaction. In this study, k(SUB)/k(ET) ratios between 5 and 10(31) were determined corresponding to Delta G(Sta)-values of 4-175 kJ mol(-1). These values cover substitution reactions going from outer-sphere electron transfer to S(N)2 with partial bond formation in the transition state. The k(SUB)/k(ET) values are round to be largest for nucleophiles such as OH- and CN- with very poor electron-donating abilities thigh oxidation potentials). When different. types of nucleophile with similar oxidation potentials are compared, a decrease in k(SUB)/k(ET) is observed going from sulfur- to carbon- and further to oxygen-centred nucleophiles. The ranking of nucleophiles in reactions involving electrophiles other than benzyl chloride is discussed with emphasis on steric hindrance and electronic effects.
• Vlasov, V. M.; Terekhova, M. I.; Petrov, E. S., Journal of Organic Chemistry USSR (English Translation), 1981, vol. 17, # 10, p. 1807 - 1813
  作者：Vlasov, V. M.、Terekhova, M. I.、Petrov, E. S.、Shatenshtein, A. I.、Yakobson, G. G.

  DOI：——

  日期：——