Z-β-chlorostyrene | 18684-86-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Z-β-chlorostyrene
• 英文别名: [(Z)-3-chloroprop-2-enyl]benzene
• CAS: 18684-86-1
• 化学式: C₉H₉Cl
• 分子量: 152.623
• InChiKey: JJTUJRVKTPSEFZ-YWEYNIOJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  3-氯-3-苄基双吖丙啶 、 富马酸二乙酯 以 异辛烷 为溶剂， 生成 diethyl 3-benzyl-3-chlorocyclopropane-1,2-dicarboxylate 、 Z-β-chlorostyrene 、 (E)-(3-chloroallyl)benzene
  参考文献：
  名称：

  将亲电子卡宾添加到缺电子的烯烃中。苄基氯卡宾-富马酸二乙酯的反应动力学

  摘要：

  苄基氯卡宾作为亲电子试剂与缺乏电子的富马酸二乙酯反应；产物比例对[DEF]的依赖性与卡宾加合物的形成一致。

  DOI：

  10.1016/s0040-4039(00)98621-0

文献信息

• End-capped polyarylene polyethers, articles made therefrom and process for preparing such polyarylene polyethers
  申请人：AMOCO CORPORATION

  公开号：EP0106023A2

  公开（公告）日：1984-04-25

  Class of high performance thermosetting materials composed of polyarylene polyether resins having each of their ends capped with a monovalent unsaturated organo radical. The end-capped polyarylene polyether resins have the formula: wherein Z and Z' are each a monovalent unsaturated organo radical. Usually Z and Z' are alkylene, aralkylene or cycloalkylene moieties. The end-capped polyarylene polyethers can be cured as is or in the presence of one or more unsaturated comonomers to afford homopolymers or copolymers, respectively. Such cured systems exhibit high glass transition temperatures, good tensile properties, excellent electric and alkali resistance and improved stress cracking resistance. End- terminated polysulfone resins having molecular weight of 5,00 to 15.000 are especially advantageous. The properties exhibited by the vinyl/allyl terminated oligomers are useful in fields which require high temperature performance, excellent solvent resistance and good fabrication characteristics. Specific areas of application include high performance molded products for appliances and electronics, high temperature laminates and adhesives and protective and insulative coatings.

  一类高性能热固性材料，由聚芳醚树脂组成，每种树脂的末端都有一个一价不饱和有机基。末端封端的聚芳基聚醚树脂的结构式如下 其中 Z 和 Z'各为一价不饱和有机基。通常 Z 和 Z' 为亚烷基、芳烷基或环烷基。末端封端的聚芳基醚可以原样固化，也可以在一种或多种不饱和共聚单体的存在下固化，分别生成均聚物或共聚物。这种固化体系具有较高的玻璃化转变温度、良好的拉伸性能、优异的耐电和耐碱性能以及更强的抗应力开裂性能。分子量在 5,00 至 15,000 之间的端末端聚砜树脂尤其具有优势。乙烯基/烯丙基端接低聚物所表现出的特性适用于需要高温性能、优异的耐溶剂性和良好的制造特性的领域。 具体应用领域包括用于电器和电子产品的高性能模塑产品、高温层压板和粘合剂以及保护性和绝缘性涂层。
• Hydrogenation of halogenated compounds
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0714875A1

  公开（公告）日：1996-06-05

  A halogenated compound I containing one or more >C=O, olefinic and/or aromatic >C=C< groups is hydrogenated for producing a halogenated compound II having no or a decreased level of >C=O, olefinic and/or aromatic >C=C< groups. In the hydrogenation process a liquid feed stream comprising one or more of these compounds I is contacted with a hydrogen-rich gaseous stream and a liquid recycle stream comprising one or more of these compounds II in the presence of a catalyst.

  含有一个或多个 >C=O、烯烃基和/或芳香族 >C=CC=O、烯烃基和/或芳香族 >C=C< 基团的卤代化合物 I。在氢化过程中，包含一种或多种此类化合物 I 的液体原料流在催化剂存在下与富氢气态流和包含一种或多种此类化合物 II 的液体循环流接触。
• HYDROGENATION OF HALOGENATED COMPOUNDS
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0794934A1

  公开（公告）日：1997-09-17
• US5914432A
  申请人：——

  公开号：US5914432A

  公开（公告）日：1999-06-22
• USH521H
  申请人：——

  公开号：USH521H

  公开（公告）日：1988-09-06