申请人:ZEON CORPORATION
公开号:EP1852447A1
公开(公告)日:2007-11-07
A nitrile group-containing copolymer rubber comprising 10 to 40wt% of α,β-ethylenically unsaturated nitrile unit (a), 10 to 60wt% of α,β-ethylenically unsaturated carboxylic acid ester unit (b), and 20 to 70wt% in total of conjugated diene unit (c) and saturated conjugated diene unit (d), wherein a content ratio "x" of a conjugated diene unit (c) based on the total content of said conjugated diene unit (c) and said saturated conjugated diene unit (d) is 0.08 or smaller, and "x·A" defined as a product of said ratio "x" and a content ratio "A" (%) of said α,β-ethylenically unsaturated nitrile unit (a) is 1.5 or smaller. According to the present invention, a nitrile group-containing copolymer rubber capable to provide a rubber vulcanizate highly balanced in mechanical strength, heat aging resistance, oil resistance, cold resistance and ozone resistance, and a vulcanizable rubber composition using the rubber can be provided.
一种含腈基的共聚橡胶,包括 10 至 40wt% 的 α,β-乙烯基不饱和腈单元(a),10 至 60wt% 的 α,β-乙烯基不饱和羧酸酯单元(b)、共轭二烯单元(c)和饱和共轭二烯单元(d)的总含量为 20 至 70wt%,其中共轭二烯单元(c)的含量比 "x "基于所述共轭二烯单元(c)和所述饱和共轭二烯单元(d)的总含量为 0.08或更小,而 "x-A "定义为所述比率 "x "与所述α,β-乙烯基不饱和腈单元(a)的含量比率 "A"(%)的乘积为1.5或更小。根据本发明,可以提供一种含腈基共聚物橡胶,该橡胶能够提供在机械强度、耐热老化性、耐油性、耐寒性和耐臭氧性方面高度平衡的橡胶硫化胶,以及使用该橡胶的可硫化橡胶组合物。