Undecafluoropentyl 2-methylprop-2-enoate | 89004-77-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Undecafluoropentyl 2-methylprop-2-enoate
• 英文别名: 1,1,2,2,3,3,4,4,5,5,5-undecafluoropentyl 2-methylprop-2-enoate
• CAS: 89004-77-3
• 化学式: C₉H₅F₁₁O₂
• 分子量: 354.12
• InChiKey: BWIUYRXKEFSAJX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  13

文献信息

• SILICON COMPOUND AND METHOD FOR PRODUCING SAME, AND USE THEREOF
  申请人：TOYO TIRE & RUBBER CO., LTD.

  公开号：US20150038643A1

  公开（公告）日：2015-02-05

  A novel silicon compound capable of initiating radical polymerization is provided. The silicon compound is represented by the following general formula (1) A-Z 1 —S—Z 2 —Si(OR 1 ) n (R 2 ) 3-n (1) wherein A is a group capable of initiating radical polymerization, Z 1 and Z 2 are each independently a bivalent group that has at least a carbon atom, R 1 and R 2 are each independently an alkyl group having from 1 to 3 carbon atoms, and n is an integer of 1 to 3. A radical polymerization initiator comprising the silicon compound, and a polymer obtained by radical polymerization of a monomer with the radical polymerization initiator are also provided. Also provided is a complex having a polymer graft chain formed on a solid substance surface with the use of the silicon compound.

  提供了一种能够启动自由基聚合的新型硅化合物。该硅化合物由以下通式(1)表示：A-Z1-S-Z2-Si（OR1）n（R2）3-n（1）其中，A是能够启动自由基聚合的基团，Z1和Z2分别是至少具有一个碳原子的双价基团，R1和R2分别是具有1至3个碳原子的烷基基团，n是1至3的整数。还提供了一种自由基聚合引发剂，其中包括该硅化合物，以及通过自由基聚合引发剂与单体进行自由基聚合得到的聚合物。还提供了一种复合物，其在固体物质表面形成了聚合物嫁接链，使用了该硅化合物。
• DIBLOCK COPOLYMER AND PRESSURE-SENSITIVE ADHESIVE COMPOSITIONS CONTAINING THE SAME
  申请人：Kuraray Co., Ltd.

  公开号：EP1489116A1

  公开（公告）日：2004-12-22

  An acrylic diblock copolymer of the general formula (I) useful in producing pressure-sensitive adhesives which are improved in cohesive force, tack and hot-melt applicability without impairing the heat resistance and weather resistance; and pressure-sensitive adhesive compositions containing the copolymer: X-Y (I)in which X is a polymer block composed of alkyl methacrylate units wherein the alkyl is one having 1 to 4 carbon atoms or one having a cyclic structure; Y is a polymer block composed of alkyl acrylate units wherein the alkyl has 1 to 20 carbon atoms and/or alkyl methacrylate units wherein the alkyl has 5 to 20 carbon atoms; the weight-average molecular weight (Mw) of X is 1,000 to 8,000; and the X/Y mass ratio ranges from 1/99 to 10/90.

  一种通式为(I)的丙烯酸二嵌段共聚物，可用于生产内聚力、粘性和热熔适用性均得到改善而耐热性和耐候性不受影响的压敏粘合剂；以及含有该共聚物的压敏粘合剂组合物：X-Y (I)，其中 X 是由甲基丙烯酸烷基酯单元组成的聚合物嵌段，其中烷基具有 1 至 4 个碳原子或具有环状结构；Y 是由丙烯酸烷基酯单元组成的聚合物嵌段，其中烷基具有 1 至 20 个碳原子和/或甲基丙烯酸烷基酯单元，其中烷基具有 5 至 20 个碳原子；X 的重量平均分子量（Mw）为 1,000 至 8,000；X/Y 的质量比为 1/99 至 10/90。
• Adhesive product and transferring instrument
  申请人：Kokuyo S&T Co.,Ltd.

  公开号：EP1683846A1

  公开（公告）日：2006-07-26

  An adhesive product which has excellent glue cutting performance and provides an excellent finish to the pasted portion while effectively maintaining security is provided. An adhesive layer 10 is formed through pattern application, where an adhesive 100 is intermittently placed on the surface of a film 12, so that a broken paper phenomenon, such that the surface layer portion of a flap F1 or the vicinity of opening F2 adheres to the surface of the adhesive layer 10, and a white envelope F is ripped in the direction of the thickness, can be caused when a peeling movement for peeling the flap F1 from a state where the white envelope F is sealed via the adhesive layer 10.

  本发明提供了一种粘合剂产品，它具有优异的切胶性能，并能在有效保持安全性的同时为粘贴部分提供出色的表面效果。粘合剂层 10 是通过图案应用形成的，其中粘合剂 100 间歇性地置于薄膜 12 的表面，因此当从通过粘合剂层 10 密封白色信封 F 的状态剥离翻盖 F1 的剥离运动时，可以产生破纸现象，例如翻盖 F1 的表层部分或开口 F2 附近粘附在粘合剂层 10 的表面，白色信封 F 沿厚度方向被撕裂。
• FLUORORESIN FILM AND FLUORORESIN-LAMINATED ACRYLIC RESIN FILM
  申请人：Kaneka Corporation

  公开号：EP2292692A1

  公开（公告）日：2011-03-09

  An object of the present invention is to provide a novel monolayer and multilayer film that can be employed also for use in interior and exterior members of vehicles, and that have excellent transparency, surface hardness, chemical resistance, and stain resistance such as lactic acid resistance and sunscreen resistance. The present invention is directed to a fluororesin film formed with (C) a fluororesin comprising (B) a fluorinated (meth)acrylic resin that contains a fluorine-containing alkyl (meth)acrylate polymer component; and a fuororesin-laminated acrylic resin film, wherein the fluororesin film layer is laminated on at least one face of a film layer comprising (A) an acrylic resin.

  本发明的目的是提供一种新型单层和多层薄膜，这种薄膜也可用于车辆的内部和外部构件，并具有优异的透明度、表面硬度、耐化学性和耐污性，例如耐乳酸性和耐晒性。本发明涉及一种由(C)氟树脂形成的氟树脂薄膜，该氟树脂包含(B)含氟(甲基)丙烯酸烷基酯聚合物成分的含氟(甲基)丙烯酸树脂；以及一种氟树脂层压丙烯酸树脂薄膜，其中氟树脂薄膜层层压在包含(A)丙烯酸树脂的薄膜层的至少一个面上。
• Fluororesin-laminated acrylic resin film
  申请人：KANEKA CORPORATION

  公开号：EP2325005A2

  公开（公告）日：2011-05-25

  An object of the present invention is to provide a novel multilayer film that can be employed also for use in interior and exterior members of vehicles, and that has excellent transparency, surface hardness, chemical resistance, and stain resistance such as lactic acid resistance and sunscreen resistance. The present invention is directed to a fluororesin-laminated acrylic resin film, wherein a fluororesin film layer comprising (B) a fluorinated (meth)acrylic resin that contains a fluorine-containing alkyl (meth)acrylate polymer component is laminated on at least one face of a film layer comprising (A) an acrylic resin.

  本发明的目的是提供一种新型多层薄膜，这种薄膜也可用于车辆的内部和外部构件，并具有优异的透明度、表面硬度、耐化学性和抗污性，例如抗乳酸和抗防晒性。本发明涉及一种氟树脂层压丙烯酸树脂薄膜，其中，在由丙烯酸树脂（A）组成的薄膜层的至少一个面上，层压了由含有含氟烷基（甲基）丙烯酸酯聚合物成分的氟化（甲基）丙烯酸树脂（B）组成的氟树脂薄膜层。