1-Isothiocyanato-4-[(4-isothiocyanatocyclohexyl)methyl]cyclohexane | 47015-38-3

• 分子结构分类: 有机化合物 - 有机硫化合物 - 异硫氰酸盐
• 英文名称: 1-Isothiocyanato-4-[(4-isothiocyanatocyclohexyl)methyl]cyclohexane
• 英文别名: 1-Isothiocyanato-4-[(4-isothiocyanatocyclohexyl)methyl]cyclohexan；4,4'-diisothiocyanatodicyclohexylmethane；bis(4-isothiocyanatocyclohexyl)methane；1,1'-Methylenebis(4-isothiocyanatocyclohexane)
• CAS: 47015-38-3
• 化学式: C₁₅H₂₂N₂S₂
• 分子量: 294.485
• InChiKey: VVDVSDSMEAAXRL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  88.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  propenoic acid 2-(2-aminoethoxy)ethyl ester 、 1-Isothiocyanato-4-[(4-isothiocyanatocyclohexyl)methyl]cyclohexane 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  [EN] UNDERWATER ADHESIVE AGENT
  [FR] AGENT ADHÉSIF SOUS-MARIN
  [JA] 水中接着剤

  摘要：

  以下の式（１）で表される化合物。 （式（１）中、ＡおよびＢは、（Ｉ）または（II）の関係を満たし、 （Ｉ）ＡおよびＢのうちの一方が下記式（２）で表される基である （II）ＡおよびＢのうちの両方が、それぞれ独立して、下記式（２）で表される基である　Ｄは水素またはメチル基である。）

  公开号：

  WO2023167269A1

文献信息

• ISOTHIOCYANATE PRODUCTION METHOD, COMPOSITION FOR TRANSPORTING AND STORING N-SUBSTITUTED O-SUBSTITUTED THIOCARBAMATE, AND ISOTHIOCYANATE COMPOSITION
  申请人：ASAHI KASEI CHEMICALS CORPORATION

  公开号：US20160016901A1

  公开（公告）日：2016-01-21

  The present invention relates to an isothiocyanate production method using an organic primary amine and thiourea as starting materials; to a composition for transporting and storing an N-substituted O-substituted thiocarbamate that includes an N-substituted O-substituted thiocarbamate and a hydroxy compound, the equivalent weight ratio of hydroxy groups of the hydroxy compound with respect to the carbamate groups of the N-substituted O-substituted thiocarbamate being in the range of 1 to 100; to a composition for transporting and storing a compound with a thioureido group that includes a compound with a thioureido group and a hydroxy compound, the equivalent weight ratio of hydroxy groups of the hydroxy compound with respect to the thioureido groups of the compound with a thioureido group being in the range of 1 to 100; and to an isothiocyanate composition containing an isothiocyanate and a compound with a specific functional group.

  该发明涉及一种使用有机初级胺和硫脲作为起始原料的异硫氰酸酯生产方法；一种用于运输和储存N-取代O-取代硫代氨基甲酸酯的组合物，包括N-取代O-取代硫代氨基甲酸酯和羟基化合物，羟基化合物的羟基与N-取代O-取代硫代氨基甲酸酯的羰基的当量重量比在1到100的范围内；一种用于运输和储存具有硫脲基团的化合物的组合物，包括具有硫脲基团的化合物和羟基化合物，羟基化合物的羟基与具有硫脲基团的化合物的硫脲基团的当量重量比在1到100的范围内；以及含有异硫氰酸酯和具有特定功能基团的化合物的异硫氰酸酯组合物。
• POLYTHIOUREA COMPOSITIONS AND METHODS OF USE
  申请人：EMPIRE TECHNOLOGY DEVELOPMENT LLC

  公开号：US20150344613A1

  公开（公告）日：2015-12-03

  Disclosed herein are compositions and methods of making polythiourea and polythiourethane foams and coatings. In one embodiment, a method of preparing a polythiourea composition involves combining at least one polyamine compound, at least one polyisothiocyanate compound, and at least one catalyst to form a reaction mixture, and mixing the reaction mixture to form the polythiourea composition. In some embodiments, the polyamine compound may have an amine functionality of two or more, and is present in an amount of about 14 wt % to about 40 wt % of the reaction mixture. In some embodiments, the polyisothiocyanate compound may have a functionality of two or more, and is present in an amount of about 60 wt % to about 86 wt % of the reaction mixture. In some embodiments, the catalyst may be present in an amount of about 0 wt % to about 5 wt % of the reaction mixture.

  本文公开了制备聚硫脲和聚硫脲酯泡沫和涂层的组合物和方法。在一种实施例中，制备聚硫脲组合物的方法包括将至少一种多胺化合物、至少一种多异硫氰酸酯化合物和至少一种催化剂组合形成反应混合物，并混合反应混合物以形成聚硫脲组合物。在一些实施例中，多胺化合物可能具有两种或更多的胺官能团，并且在反应混合物中的含量约为14重量％至约40重量％。在一些实施例中，多异硫氰酸酯化合物可能具有两种或更多的官能团，并且在反应混合物中的含量约为60重量％至约86重量％。在一些实施例中，催化剂可能在反应混合物中的含量约为0重量％至约5重量％。
• Improved processable radiation curable poly(vinyl chloride) resin compositions
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0132032A2

  公开（公告）日：1985-01-23

  This invention relates to radiation-curable poly(vinyl chloride) resin compositions that can be processed to form shaped articles, coatings, and films. Poly(vinyl chloride) resins are generally characterized by low impact strength. To remedy this shortcoming, radiation curing of compositions of poly(vinyl chloride) resins containing various plasticizers and crosslinking agents has been utlized. However, certain cross- linking agents cause radiation-cured poly(vinyl chloride) resins to become cloudy and exude oily materials upon storage. It has been discovered that poly(vinyl chloride) resin compositions containing an ethylenically-unsaturated compound having carbonylamino or thiocarbonylamino groups are readily convertible at low temperatures to crosslinked polymers and are radiation-curable to dimensionally stable articles and films that are clear and that do not exude oily materials. The cured poly(vinyl chloride) resin compositions of the invention are useful in the form of such shaped articles as self-supporting films, foils, and sheets and as coatings. The compositions of this invention are particularly useful as a sheet for a tape support for an adhesive and as coating compositions for substrates such as wire and flat cable insulation.

  本发明涉及辐射固化聚（氯乙烯）树脂组合物，该组合物可加工成成型物品、涂层和薄膜。聚氯乙烯树脂通常具有冲击强度低的特点。为了弥补这一缺陷，人们利用辐射固化含有各种增塑剂和交联剂的聚氯乙烯树脂组合物。然而，某些交联剂会导致辐射固化的聚氯乙烯树脂在储存时变得浑浊并渗出油状物。 现已发现，含有一种具有羰基氨基或硫代羰基氨基的乙烯基不饱和化合物的聚氯乙烯树脂组合物在低温下很容易转化为交联聚合物，并通过辐射固化成尺寸稳定、透明且不渗出油性物质的物品和薄膜。 本发明的固化聚氯乙烯树脂组合物可用于自支撑薄膜、箔和片材等形状的物品以及涂层。本发明的组合物尤其可用作粘合剂的胶带支撑片材，以及电线和扁平电缆绝缘层等基材的涂层组合物。
• Derivatives of N-hals-substituted amic acid hydrazides
  申请人：ELF ATOCHEM NORTH AMERICA, INC.

  公开号：EP0434080A1

  公开（公告）日：1991-06-26

  N-(2,2,6,6-tetraalkyl-4-piperidinyl)amic acid hydrazides contain a light stabilizing group, a heat stabilizing group and an amic acid hydrazide functionality in the same molecule. The amic acid hydrazide functionality in the compounds enhances the photooxidative stabilizing properties of the hindered amine groups and contributes thermal and oxidative stabilizing and metal complexing properties to the compounds. The novel compounds are excellent light stabilizers for polyolefins, have low volatility and are not readily lost from polymeric systems via volatilization, migration or extraction.

  N-(2,2,6,6-四烷基-4-哌啶基)胺基酸酰肼在同一分子中含有光稳定基团、热稳定基团和胺基酸酰肼官能团。化合物中的胺酸酰肼官能团增强了受阻胺基团的光氧化稳定特性，并使化合物具有热稳定、氧化稳定和金属络合特性。这些新型化合物是聚烯烃的优良光稳定剂，挥发性低，不易通过挥发、迁移或萃取从聚合物体系中流失。
• Hindered amine light stabilizer hydrazides
  申请人：ELF ATOCHEM NORTH AMERICA, INC.

  公开号：EP0467344A1

  公开（公告）日：1992-01-22

  New and novel carboxylic acid hydrazides bearing a 2,2,6,6-tetra-alkyl-4-piperidine ring and new and novel polymeric compositions stabilized therewith are provided. The novel compounds which contain a light stabilizing group and a reactive hydrazide functionality in the same molecule are prepared by hydrazinolysis of the ester group of an intermediate carboxylic acid ester which contains the 2,2,6,6-tetralkylpiperidine moiety.

  本发明提供了含有 2，2，6，6-四烷基-4-哌啶环的新型羧酸酰肼以及用其稳定的新型聚合物组合物。这些新型化合物在同一分子中含有光稳定基团和活性酰肼官能团，其制备方法是对含有 2,2,6,6- 四烷基哌啶分子的中间羧酸酯的酯基进行酰肼水解。