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allyl 3-methyl-5,6,7,8-tetrahydrocinnoline-4-carboxylate | 1242030-47-2

中文名称
——
中文别名
——
英文名称
allyl 3-methyl-5,6,7,8-tetrahydrocinnoline-4-carboxylate
英文别名
——
allyl 3-methyl-5,6,7,8-tetrahydrocinnoline-4-carboxylate化学式
CAS
1242030-47-2
化学式
C13H16N2O2
mdl
——
分子量
232.282
InChiKey
BVFCAPYAXRPYQX-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    2.01
  • 重原子数:
    17.0
  • 可旋转键数:
    3.0
  • 环数:
    2.0
  • sp3杂化的碳原子比例:
    0.46
  • 拓扑面积:
    52.08
  • 氢给体数:
    0.0
  • 氢受体数:
    4.0

反应信息

  • 作为产物:
    描述:
    allyl 3-methyl-2,4a,5,6,7,8-hexahydrocinnoline-4-carboxylate2,3-二氯-5,6-二氰基-1,4-苯醌 作用下, 以 二氯甲烷 为溶剂, 以94%的产率得到allyl 3-methyl-5,6,7,8-tetrahydrocinnoline-4-carboxylate
    参考文献:
    名称:
    Divergent base-induced reactivity of cycloalkenyl-1-diazenes
    摘要:
    The different base-promoted regioselectivities of the ring closure processes in the reactions between cycloalkenyl-1-diazenes and beta-ketoesters are investigated. Under the appropriate conditions it is possible to turn the synthesis towards cycloalkenyliden-pyrroles or functionalized 3-hydroxy-hydrocinnolines. The aromatization procedure of the heteroring counterpart of the 3-hydroxy-hydrocinnolines is also reported. (C) 2010 Elsevier Ltd. All rights reserved.
    DOI:
    10.1016/j.tet.2010.06.061
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文献信息

  • Divergent base-induced reactivity of cycloalkenyl-1-diazenes
    作者:Orazio A. Attanasi、Stefano Berretta、Lucia De Crescentini、Gianfranco Favi、Paolino Filippone、Gianluca Giorgi、Fabio Mantellini
    DOI:10.1016/j.tet.2010.06.061
    日期:2010.8
    The different base-promoted regioselectivities of the ring closure processes in the reactions between cycloalkenyl-1-diazenes and beta-ketoesters are investigated. Under the appropriate conditions it is possible to turn the synthesis towards cycloalkenyliden-pyrroles or functionalized 3-hydroxy-hydrocinnolines. The aromatization procedure of the heteroring counterpart of the 3-hydroxy-hydrocinnolines is also reported. (C) 2010 Elsevier Ltd. All rights reserved.
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