1-phenyl-2,2-bis(trifluoromethanesulfonyl)ethylene | 58510-69-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-phenyl-2,2-bis(trifluoromethanesulfonyl)ethylene
• 英文别名: β,β-Bis-trifluormethylsulfonyl-styrol；β,β-bis[(trifluoromethyl)sulfonyl]styrene；β,β-bis(perfluoromethylsulfonyl)-styrene；b,b-bis[(trifluoromethyl)sulfonyl]styrene；[2,2-Bis(trifluoromethanesulfonyl)ethenyl]benzene；2,2-bis(trifluoromethylsulfonyl)ethenylbenzene
• CAS: 58510-69-3
• 化学式: C₁₀H₆F₆O₄S₂
• 分子量: 368.278
• InChiKey: LYVKURBLYHQGEP-UHFFFAOYSA-N

物化性质

• 沸点：
  434.8±45.0 °C(Predicted)
• 密度：
  1.662±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  85
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  1-phenyl-2,2-bis(trifluoromethanesulfonyl)ethylene 、 4-(4-氯苯基)-2-(三氟甲基)-2H-1,3-恶唑-5-酮 在 三乙胺 作用下， 以 N-甲基乙酰胺 、 乙酸乙酯 为溶剂， 生成 2-(p-Chlorophenyl)-4-phenyl-5-(trifluoromethyl)-3-[(trifluoromethyl)sulfonyl]pyrrole
  参考文献：
  名称：

  Haloalkylthio, -sulfinyl and -sulfonyl arylpyrrole insecticidal and

  摘要：

  描述了对昆虫和螨虫有效的卤代硫基、-亚砜基和-砜基芳基吡咯烷化合物。提供了利用这些化合物进行杀虫和杀螨的方法，以及制备这些化合物的方法。

  公开号：

  US05306827A1
• 作为产物：
  描述：

  双[(三氟代甲基)磺酰基]甲烷 、 苯甲醛 以 乙酸酐 为溶剂， 反应 12.0h， 以90%的产率得到1-phenyl-2,2-bis(trifluoromethanesulfonyl)ethylene
  参考文献：
  名称：

  Synthesis and Reactions of 1-Aryl-2,2-bis(perfluoroalkanesulfonyl)ethylenes

  摘要：

  通过双（全氟烷磺酰基）甲烷 1 与芳香醛的缩合制备了标题化合物 3，产量很高。 研究了 3 与吡啶和亚磷酸二甲酯的反应。

  DOI：

  10.1055/s-1994-25454

文献信息

• Synthesis and Reactions of 1-Aryl-2,2-bis(perfluoroalkanesulfonyl)ethylenes
  作者：Shi-Zheng Zhu

  DOI：10.1055/s-1994-25454

  日期：——

  The title compounds 3 were prepared by condensation of bis (perfluoroalkanesulfonyl)methanes 1 with aromatic aldehydes in high yields. Reactions of 3 with pyridine and dimethyl phosphite were studied.

  通过双（全氟烷磺酰基）甲烷 1 与芳香醛的缩合制备了标题化合物 3，产量很高。 研究了 3 与吡啶和亚磷酸二甲酯的反应。
• A CATALYST FOR HOMOPOLYMERIZING AND COPOLYMERIZING PROPYLENE AND ITS PREPARATION AND USE
  申请人：Petrochina Company Limited

  公开号：EP2345675A1

  公开（公告）日：2011-07-20

  A catalyst for homopolymerizing and copolymerizing propylene and its preparation and use. The catalyst component includes titanium compound containing at least one Ti-halogen bond and at least two kinds of electron donor compounds A and B supported on MgCl2.nROH adduct, wherein the electron donor compound A is a compound of formula (I), the electron donor compound B is ester or ether compound; the molar ratio between compound A and compound B is 0.1-5; the molar ratio between the total amounts of the two kinds of electron donors and MgCl2.nROH is 0.01-1, based on the amount of MgCl2.nROH; and the molar ration between the titanium compound containing Ti-halogen bond and MgCl2.nROH is 1-200. The catalyst has high activity high stereospecificity and good copolymerization performance. In addition, the morphology of the polymer obtained therefrom is good.

  一种用于均聚和共聚丙烯的催化剂及其制备和使用方法。催化剂组分包括含有至少一个钛卤键的钛化合物和至少两种支撑在 MgCl2.nROH 加合物上的电子供体化合物 A 和 B，其中电子供体化合物 A 为式（I）化合物，电子供体化合物 B 为酯或醚化合物；化合物 A 和化合物 B 的摩尔比为 0.1-5；以MgCl2.nROH的量计，两种电子供体与MgCl2.nROH总量的摩尔比为0.01-1；含Ti-卤素键的钛化合物与MgCl2.nROH的摩尔比为1-200。该催化剂具有高活性、高立体特异性和良好的共聚性能。此外，由此获得的聚合物的形态也很好。
• Haloalkylthio, -sulfinyl and -sulfonyl arylpyrrole insecticidal, acaricidal and fungicidal agents
  申请人：American Cyanamid Company

  公开号：EP0549866B1

  公开（公告）日：1997-08-13
• OLEFIN POLYMERIZATION CATALYST AND PREPARATION METHOD AND USE THEREOF
  申请人：Petrochina Company Limited

  公开号：EP2159232B1

  公开（公告）日：2012-11-21
• CATALYST FOR HOMOPOLYMERIZING AND COPOLYMERIZING PROPYLENE AND ITS PREPARATION AND USE
  申请人：Yi Jianjun

  公开号：US20110207900A1

  公开（公告）日：2011-08-25

  A catalyst for homopolymerizing and copolymerizing propylene and its preparation and use. The catalyst component includes titanium compound containing at least one Ti-halogen bond and at least two kinds of electron donor compounds A and B supported on MgCl 2 .nROH adduct, wherein the electron donor compound A is a compound of formula (I), the electron donor compound B is ester or ether compound; the molar ratio between compound A and compound B is 0.1-5; the molar ratio between the total amounts of the two kinds of electron donors and MgCl 2 .nROH is 0.01-1, based on the amount of MgCl 2 .nROH; and the molar ration between the titanium compound containing Ti-halogen bond and MgCl 2 .nROH is 1-200. The catalyst has high activity, high stereospecificity and good copolymerization performance. In addition, the morphology of the polymer obtained therefrom is good.