3'''-Bromo-2',5'-dihexyl-4-iodo-[1,4';1',1'';4'',1''']quaterphenyl | 221677-84-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3'''-Bromo-2',5'-dihexyl-4-iodo-[1,4';1',1'';4'',1''']quaterphenyl
• CAS: 221677-84-5
• 化学式: C₃₆H₄₀BrI
• 分子量: 679.522
• InChiKey: VONZCSQLNLMOEF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.3
• 重原子数：
  38.0
• 可旋转键数：
  13.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  3'''-Bromo-2',5'-dihexyl-4-iodo-[1,4';1',1'';4'',1''']quaterphenyl 、 在 barium dihydroxide 、 四(三苯基膦)钯 作用下， 以 水 、 甲苯 为溶剂， 反应 72.0h， 以85%的产率得到
  参考文献：
  名称：

  A Cyclotetraicosaphenylene

  摘要：

  Suzuki cross-coupling of kinked oligophenylene building blocks is used for the repetitive synthesis of large hexagons, which as a result of their substitution with flexible alkyl chains are soluble in common organic solvents. Cycle 15 with its 24 phenylene units is the largest shape persistent cycle known. The last cyclization step proceeds with 68% yield.

  DOI：

  10.1002/(sici)1521-3765(19990201)5:2<421::aid-chem421>3.0.co;2-d
• 作为产物：
  描述：

  3-溴-4'-碘-1,1'-联苯 在 barium dihydroxide 、 四(三苯基膦)钯 、 一氯化碘 作用下， 以 二氯甲烷 、 水 、 甲苯 为溶剂， 反应 72.5h， 生成 3'''-Bromo-2',5'-dihexyl-4-iodo-[1,4';1',1'';4'',1''']quaterphenyl
  参考文献：
  名称：

  A Cyclotetraicosaphenylene

  摘要：

  Suzuki cross-coupling of kinked oligophenylene building blocks is used for the repetitive synthesis of large hexagons, which as a result of their substitution with flexible alkyl chains are soluble in common organic solvents. Cycle 15 with its 24 phenylene units is the largest shape persistent cycle known. The last cyclization step proceeds with 68% yield.

  DOI：

  10.1002/(sici)1521-3765(19990201)5:2<421::aid-chem421>3.0.co;2-d

文献信息

• A Cyclotetraicosaphenylene
  作者：Volker Hensel、A. Dieter Schlüter

  DOI：10.1002/(sici)1521-3765(19990201)5:2<421::aid-chem421>3.0.co;2-d

  日期：1999.2.1

  Suzuki cross-coupling of kinked oligophenylene building blocks is used for the repetitive synthesis of large hexagons, which as a result of their substitution with flexible alkyl chains are soluble in common organic solvents. Cycle 15 with its 24 phenylene units is the largest shape persistent cycle known. The last cyclization step proceeds with 68% yield.