[RuCl2(η1:η6-Cy2P(CH2)3Ph)] | 222168-35-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [RuCl2(η1:η6-Cy2P(CH2)3Ph)]
• CAS: 222168-35-6
• 化学式: C₂₁H₃₃Cl₂PRu
• 分子量: 488.443
• InChiKey: LDZFWXOJMYSALI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [RuCl2(p-cymene)(dicyclohexyl(3-phenylpropyl)phosphine)] 以 氯苯 为溶剂， 以82%的产率得到[RuCl2(η1:η6-Cy2P(CH2)3Ph)]
  参考文献：
  名称：

  Synthesis and evaluation of new RuCl2(p-cymene)(ER2R′) and (η1:η6-phosphinoarene)RuCl2 complexes as ring-opening metathesis polymerization catalysts

  摘要：

  New RuCl2(p-cymene)(ER2R') complexes (E = P, As, Sb; R, R' = H, alkyl, arylalkyl) have been synthesized and used as catalyst precursors for the ring-opening metathesis polymerization (ROMP) of cyclooctene, cyclopentene, and norbornene. When ER2R' was a phosphinoarene, the p-cymene ligand could be displaced upon heating and tethered (eta(1):eta(6)-phosphinoarene)RuCl2 complexes were obtained. Simple thermogravimetric analysis (TGA) of the complexes provided clear-cut indication on their potential catalytic activity in ROMP. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00287-4

文献信息

• Synthesis and evaluation of new RuCl2(p-cymene)(ER2R′) and (η1:η6-phosphinoarene)RuCl2 complexes as ring-opening metathesis polymerization catalysts
  作者：Dominique Jan、Lionel Delaude、François Simal、Albert Demonceau、Alfred F Noels

  DOI：10.1016/s0022-328x(00)00287-4

  日期：2000.7

  New RuCl2(p-cymene)(ER2R') complexes (E = P, As, Sb; R, R' = H, alkyl, arylalkyl) have been synthesized and used as catalyst precursors for the ring-opening metathesis polymerization (ROMP) of cyclooctene, cyclopentene, and norbornene. When ER2R' was a phosphinoarene, the p-cymene ligand could be displaced upon heating and tethered (eta(1):eta(6)-phosphinoarene)RuCl2 complexes were obtained. Simple thermogravimetric analysis (TGA) of the complexes provided clear-cut indication on their potential catalytic activity in ROMP. (C) 2000 Elsevier Science S.A. All rights reserved.