2-isopropyl-6-phenylphenol | 918151-47-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-isopropyl-6-phenylphenol
• 英文别名: 3-isopropyl[1,1'-biphenyl]-2-ol；2-phenyl-6-propan-2-ylphenol
• CAS: 918151-47-0
• 化学式: C₁₅H₁₆O
• 分子量: 212.291
• InChiKey: UGDCVLOYOWWPQS-UHFFFAOYSA-N

物化性质

• 沸点：
  325.7±21.0 °C(Predicted)
• 密度：
  1.044±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-isopropyl-6-phenylphenol 以 正己烷 、 甲苯 为溶剂， 以64%的产率得到(dichloro)(pentamethylcyclopentadienyl)(2-isopropyl-6-phenylphenoxy)titanium
  参考文献：
  名称：

  ARYLPHENOXY CATALYST SYSTEM FOR PRODUCING ETHYLENE HOMOPOLYMER OR COPOLYMERS OF ETHYLENE AND ALPHA-OLEFINS

  摘要：

  公开号：

  EP1910427B1
• 作为产物：
  描述：

  碘苯 在 chloro(1,5-cyclooctadiene)rhodium(I) dimer 、 间氯过氧苯甲酸 、 lithium tert-butoxide 、 三(二甲胺基)膦 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 反应 14.0h， 生成 2-isopropyl-6-phenylphenol
  参考文献：
  名称：

  P(NMe2)3-promoted ortho-selective arylation of phenols with diaryliodonium triflates via rhodium catalysis

  摘要：

  Rh-catalyzed ortho-selective arylation of free phenol with diaryliodonium triflates to widely existed phenol-containing biaryls have been developed. The use of P(NMe2)(3), (BuOLi)-Bu-t and CH3CN proved to be critical for the ortho-selectivity of this reaction. (C) 2017 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2017.03.055

文献信息

• Hydroxyphenyl adamantanes and process for the production of the same
  申请人：——

  公开号：US20030187307A1

  公开（公告）日：2003-10-02

  Hydroxyphenyl adamantanes are represented by the general formula (1): 1 wherein R is an alkyl group, cycloalkyl group or phenyl group; m is 0 or an integer 1 or 2; l is 0 or 1; when l is 1, hydroxy groups of substituted hydroxyphenyl groups at positions 1 and 3 are together in para-position; n is 0 or an integer 1, 2 or 3; and when l is 0, n is an integer 1, 2 or 3.

  羟基苯基重氮烷类化合物由通式（1）表示： 1 其中R为烷基、环烷基或苯基；m为0或整数1或2；l为0或1；当l为1时，取代羟基苯基的1和3位的羟基在对位上共同存在；n为0或整数1、2或3；当l为0时，n为整数1、2或3。
• ARYLPHENOXY CATALYST SYSTEM FOR PRODUCING ETHYLENE HOMOPOLYMER OR COPOLYMERS OF ETHYLENE AND a-OLEFINS
  申请人：Woo Tae Woo

  公开号：US20090326175A1

  公开（公告）日：2009-12-31

  The present invention relates to an arylphenoxy catalyst system producing an ethylene homopolymer or copolymers of ethylene and α-olefins, and a method of producing an ethylene homopolymer or copolymers of ethylene and α-olefins having a high molecular weight under a high temperature solution polymerization condition using the same. The catalyst system includes a group IV arylphenoxy-based transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst. In the transition metal catalyst, a cyclopentadiene derivative and arylphenoxide as fixed ligands are located around the group IV transition metal, arylphenoxide is substituted with at least one aryl derivative and is located at the ortho position thereof, and the ligands are not crosslinked to each other. The catalyst includes an environmentally-friendly raw material, synthesis of the catalyst is economical, and thermal stability of the catalyst is excellent. It is useful for producing an ethylene homopolymer or copolymers of ethylene and α-olefins having various physical properties in commercial polymerization processes.

  本发明涉及一种芳基苯氧基催化剂体系，用于生产乙烯均聚物或乙烯与α-烯烃的共聚物，并且提供了一种在高温溶液聚合条件下生产具有高分子量的乙烯均聚物或乙烯与α-烯烃共聚物的方法。该催化剂体系包括一种基于IV族过渡金属的芳基苯氧基催化剂和一种铝氧烷共催化剂或硼化合物共催化剂。在过渡金属催化剂中，环戊二烯衍生物和芳基酚氧化物作为固定配体位于IV族过渡金属周围，芳基酚氧化物被至少一个芳基衍生物取代，并位于其邻位，配体之间不交联。该催化剂包含一种环保的原材料，催化剂的合成经济，催化剂的热稳定性优异。在商业聚合过程中，对生产具有各种物理性质的乙烯均聚物或乙烯与α-烯烃共聚物非常有用。
• Arylphenoxy catalyst system for producing ethylene homopolymer or copolymers of ethylene and alpha-olefins
  申请人：Woo Woo Tae

  公开号：US20070004586A1

  公开（公告）日：2007-01-04

  The present invention relates to an arylphenoxy catalyst system producing an ethylene homopolymer or copolymers of ethylene and α-olefins, and a method of producing an ethylene homopolymer or copolymers of ethylene and α-olefins having a high molecular weight under a high temperature solution polymerization condition using the same. The catalyst system includes a group IV arylphenoxy-based transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst. In the transition metal catalyst, a cyclopentadiene derivative and arylphenoxide as fixed ligands are located around the group IV transition metal, arylphenoxide is substituted with at least one aryl derivative and is located at the ortho position thereof, and the ligands are not crosslinked to each other. The catalyst includes an environmentally-friendly raw material, synthesis of the catalyst is economical, and thermal stability of the catalyst is excellent. It is useful for producing an ethylene homopolymer or copolymers of ethylene and α-olefins having various physical properties in commercial polymerization processes.

  本发明涉及一种芳基苯氧催化剂体系，用于生产乙烯均聚物或乙烯和α-烯烃共聚物，并且提供了一种在高温溶液聚合条件下制备高分子量乙烯均聚物或乙烯和α-烯烃共聚物的方法。该催化剂体系包括一个IV族芳基苯氧过渡金属催化剂和一个氧化铝烷共催化剂或硼化合物共催化剂。在过渡金属催化剂中，一个环戊二烯衍生物和苯氧基作为固定配体位于IV族过渡金属周围，苯氧基被至少一个苯基衍生物取代，并位于其邻位位置，而配体之间不交联。该催化剂包含一种环保的原料，催化剂的合成经济实惠，催化剂的热稳定性优异。它在商业聚合过程中有助于生产具有各种物理性质的乙烯均聚物或乙烯和α-烯烃共聚物。
• ETHYLENE COPOLYMER AND A METHOD OF PREPARING THE SAME
  申请人：Shin Daeho

  公开号：US20100120981A1

  公开（公告）日：2010-05-13

  Provided are ethylene copolymers and a process for preparing the same. More specifically, provided are ethylene copolymers exhibiting excellent processibility and physical properties due to its multimodal molecular weight distribution index, through a multi-stage process by using reactors connected in series or in parallel in the presence of catalyst composition containing transition metal catalyst, and a process for preparing the same.

  提供了乙烯共聚物及其制备方法。更具体地，通过使用串联或并联连接的反应器中存在过渡金属催化剂的催化剂组合物的多阶段过程，提供了具有多峰分子量分布指数的乙烯共聚物，其表现出优异的加工性能和物理性能，以及其制备方法。
• Ethylene copolymer and a method of preparing the same
  申请人：SK Innovation Co., Ltd.

  公开号：US08067511B2

  公开（公告）日：2011-11-29

  Provided are ethylene copolymers and a process for preparing the same. More specifically, provided are ethylene copolymers exhibiting excellent processibility and physical properties due to its multimodal molecular weight distribution index, through a multi-stage process by using reactors connected in series or in parallel in the presence of catalyst composition containing transition metal catalyst, and a process for preparing the same.

  本发明提供了乙烯共聚物及其制备方法。更具体地，本发明提供了一种通过使用串联或并联连接的反应器，在过渡金属催化剂组成物的存在下，通过多阶段过程制备具有多峰分子量分布指数的乙烯共聚物，其具有优异的加工性和物理性能的乙烯共聚物，以及其制备方法。