1,2,3-trivinyloxypropane | 3891-35-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 1,2,3-trivinyloxypropane
• 英文别名: 1,2,3-Tris-vinyloxy-propan；1,2,3-Tris(ethenyloxy)propane；1,2,3-tris(ethenoxy)propane
• CAS: 3891-35-8
• 化学式: C₉H₁₄O₃
• mdl: MFCD01839121
• 分子量: 170.208
• InChiKey: CGXVUIBINWTLNT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2909199090

反应信息

• 作为反应物：
  描述：

  1,2,3-trivinyloxypropane 在 盐酸 、 乙醇 作用下， 生成 trans-4-hydroxymethyl-2-methyl-1,3-dioxolane
  参考文献：
  名称：

  Schostakowskii et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1955, p. 350,353; engl. Ausg. S. 313, 315

  摘要：

  DOI：
• 作为产物：
  描述：

  甘油 、 乙炔 在 氢氧化钾 作用下， 170.0 ℃ 、1.18 MPa 条件下， 生成 1,2,3-trivinyloxypropane
  参考文献：
  名称：

  Faworski; Schostakowski, Zhurnal Obshchei Khimii, 1943, vol. 13, p. 15

  摘要：

  DOI：

文献信息

• DIENE-BASED CARBOXYLATE ANION AND SALT THEREOF, AND POLYMERIZABLE OR CURABLE COMPOSITION THEREOF
  申请人：Kaneko Tomomasa

  公开号：US20130197123A1

  公开（公告）日：2013-08-01

  The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.

  所述发明提供了一种新颖的化合物，此化合物以前未被研究过，即一种含有特定结构的二烯二酸盐阴离子及其盐。所述发明进一步提供了一种二烯二酸盐阴离子及其盐，特别是其金属盐，这些盐在一般有机溶剂、反应性稀释剂和树脂中易溶解，在常温下可能处于液态，具有高聚合性。这些的聚合/固化产生的树脂引入了许多离子键和金属，提供了硬度、抗刮擦性、防指纹性、气体屏障性、阻水汽性、氧气吸收性、紫外线保护、红外线保护、颜色开发和着色、高折射率、粘附性、各种催化能力、荧光能力和发光能力、光学放大、分散性和抗静电性等各种性能。此外，该阴离子和盐可用作功能性细颗粒和金属纳米粒子复合材料的原材料，也可用于MOD材料。所述发明还提供了一种生产二烯二酸盐阴离子及其盐的优势方法。
• [EN] ACYLPHOSPHINE OXIDE PHOTOINITIATORS<br/>[FR] PHOTO-INITIATEURS À BASE D'OXYDE D'ACYLPHOSPHINE
  申请人：AGFA GRAPHICS NV

  公开号：WO2017191043A1

  公开（公告）日：2017-11-09

  Thiol modified acylphosphine oxide photoinitiators exhibiting improved smell and extractability are disclosed. Also disclosed is a UV curable inkjet ink containing an acylphosphine oxide photoinitiator and a polymerizable compound, wherein the acylphosphine oxide photoinitiator includes one or more acyl groups substituted by a thiol.

  揭示了改善气味和可提取性的硫醇改性酰基膦氧化物光引发剂。还揭示了一种含有酰基膦氧化物光引发剂和可聚合化合物的紫外固化喷墨墨水，其中酰基膦氧化物光引发剂包括一个或多个由硫醇取代的酰基。
• Direct vinylation of natural alcohols and derivatives with calcium carbide
  作者：Siew Ping Teong、Ariel Yi Hui Chua、Shiyun Deng、Xiukai Li、Yugen Zhang

  DOI：10.1039/c6gc03579e

  日期：——

  A transition metal-free, mild, and safe protocol has been developed for direct vinylation of various sugar alcohols, phenol and its derivatives with calcium carbide.

  已经开发了一种无过渡金属，温和且安全的规程，用于将各种糖醇，苯酚及其衍生物与电石直接乙烯基化。
• Synthesis of Functional Tripodal Phosphines with Amino and Ether Groups by the Hydrophosphination of Trivinyl Ethers with Secondary Phosphines
  作者：Boris Trofimov、Ludmila Oparina、Nina Gusarova、Oksana Vysotskaya、Alexander Artem’ev、Nikita Kolyvanov

  DOI：10.1055/s-0033-1340497

  日期：——

  halogen-free synthesis of functional triphosphines with nitrogen and (or) oxygen atoms­ as additional weaker coordinating sites (new hemilabile ligands) through exhaustive addition of secondary phosphines to available trivinyl ethers of aminotriols and triols has been developed. The reaction proceeds under free-radical conditions (UV irradiation or AIBN, with 3:1 reactant molar ratio) to give chemo- and

  摘要 通过将仲膦穷尽地添加到氨基三醇的三乙烯基醚中，将一氧化氮与（和）氧原子作为其他较弱的配位位点（新的半不稳定配体）进行一锅，无原子经济，无金属和卤素的合成已开发出三醇。反应在自由基条件下进行（UV辐射或AIBN，反应物摩尔比为3：1），从而以良好或优异的收率为所有三个乙烯基氧基提供化学和区域选择性的反马尔科夫尼科夫三加合物。 通过将仲膦穷尽地添加到氨基三醇的三乙烯基醚中，将一氧化氮与（和）氧原子作为其他较弱的配位位点（新的半不稳定配体）进行一锅，无原子经济，无金属和卤素的合成已开发出三醇。反应在自由基条件下进行（UV辐射或AIBN，反应物摩尔比为3：1），从而以良好或优异的收率为所有三个乙烯基氧基提供化学和区域选择性的反马尔科夫尼科夫三加合物。
• Sulfonium salt, curable composition, ink composition, inkjet recording method, printed material, process for producing lithographic printing plate, and lithographic printing plate
  申请人：Tsuchimura Tomotaka

  公开号：US20070197677A1

  公开（公告）日：2007-08-23

  A sulfonium salt is provided that has a cation represented by Formula (II) (R 1′ to R 13′ in Formula (II) independently denote a hydrogen atom or a substituent, and may be bonded to each other to form a ring, provided that at least one of R 1′ to R 8′ denotes a halogen atom or a haloalkyl group). There are also provided a curable composition that includes the sulfonium salt, and an ink composition that includes the curabie composition. Furthermore, there are also provided an inkjet recording method employing the ink composition, and a process for producing a lithographic printing plate, the process including discharging the ink composition onto a hydrophilic support. A printed material and a lithographic printing plate thus obtained are also included in the present invention.

  提供一种具有由化学式（II）表示的阳离子的硫铵盐（其中，化学式（II）中的R1'到R13'独立地表示氢原子或取代基，并且它们可以结合在一起形成环，前提是R1'到R8'中至少有一个表示卤素原子或卤代烷基）。还提供了包括该硫铵盐的可固化组合物，以及包括该可固化组合物的油墨组合物。此外，还提供了一种采用该油墨组合物的喷墨记录方法，以及生产平版印刷版的工艺，其中该工艺包括将油墨组合物排放到亲水性支撑体上。本发明还包括由此获得的印刷材料和平版印刷版。