2-(4-Methyl-4-pentenyl)phthalimide | 86611-76-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: 2-(4-Methyl-4-pentenyl)phthalimide
• 英文别名: 2-(4-Methylpent-4-enyl)isoindole-1,3-dione
• CAS: 86611-76-9
• 化学式: C₁₄H₁₅NO₂
• 分子量: 229.279
• InChiKey: CDJJSZVGNGDWEO-UHFFFAOYSA-N

物化性质

• 沸点：
  178 °C(Press: 1 Torr)
• 密度：
  1.140±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(4-Methyl-4-pentenyl)phthalimide 以 乙腈 为溶剂， 生成 6a-methyl-6,7,8,9-tetrahydropyrrolo[1,2-b][2]benzazepine-5,11-dione
  参考文献：
  名称：

  Photochemical additions of alkenes to phthalimides. Mechanistic investigations on the stereochemistry of alkene additions and the effect of aryl substituents on the regiochemistry of alkene additions

  摘要：

  DOI：

  10.1021/jo00166a009
• 作为产物：
  描述：

  4-甲基-4-戊烯酸乙酯 在 吡啶 、 lithium aluminium tetrahydride 、 lithium bromide 作用下， 以 乙醚 、 N,N-二甲基甲酰胺 、 丙酮 为溶剂， 反应 28.0h， 生成 2-(4-Methyl-4-pentenyl)phthalimide
  参考文献：
  名称：

  Photochemical additions of alkenes to phthalimides. Mechanistic investigations on the stereochemistry of alkene additions and the effect of aryl substituents on the regiochemistry of alkene additions

  摘要：

  DOI：

  10.1021/jo00166a009

文献信息

• Direct free-radical substitutions on allyl and vinyl halides using alkyl halides/hexabutylditin
  作者：Chad C. Huval、Daniel A. Singleton

  DOI：10.1016/s0040-4039(00)93373-2

  日期：1993.5

  Allyl and vinyl halides are excellent acceptors for tin-mediated substitutions by alkyl radicals generated from alkyl halides.

  烯丙基和乙烯基卤化物是由烷基卤化物生成的烷基进行锡介导取代的极佳受体。
• Decarbonylative Transfer Hydrochlorination of Alkenes and Alkynes Based on a B(C ₆ F ₅ ) ₃ ‐Initiated Grob Fragmentation
  作者：Kaixue Xie、Martin Oestreich

  DOI：10.1002/anie.202203692

  日期：2022.6.13

  fragmentation of cyclohexa-2,5-dien-1-yl-substituted acyl chlorides into a low-molecular-weight arene, carbon monoxide and HCl. In the presence of π-basic substrates such as alkenes and alkynes, HCl is transferred stepwise to afford the corresponding hydrochlorination products. The overall reaction is a decarbonylative transfer hydrochlorination driven by aromatization and carbon-monoxide release.

  B(C 6 F 5 ) 3引发 cyclohexa-2,5-dien-1-yl-取代的酰氯的 Grob 裂解为低分子量芳烃、一氧化碳和 HCl。在 π 碱性底物（如烯烃和炔烃）存在下，逐步转移 HCl 以提供相应的氢氯化产物。整个反应是由芳构化和一氧化碳释放驱动的脱羰转移氢氯化反应。
• Chiral Hypervalent Iodine Catalysis Enables an Unusual Regiodivergent Intermolecular Olefin Aminooxygenation
  作者：Fan Wu、Navdeep Kaur、Nur-E Alom、Wei Li

  DOI：10.1021/jacsau.1c00103

  日期：2021.6.28

  strategy is described here. Amide is used as the O- and N- source to probe for regiocontrol strategies. Notably, simple additives can be selectively introduced to achieve regiodivergent oxyamination processes for electronically activated alkenes while being regio-complementary for unactivated alkenes. Our preliminary data demonstrates that this regiocontrol strategy based on nucleophile can also be applied

  本文描述了一种新型碘化物催化分子间氨氧化策略。酰胺用作 O 源和 N 源来探测区域控制策略。值得注意的是，可以选择性地引入简单的添加剂，以实现电子活化烯烃的区域发散的氧胺化过程，同时对未活化的烯烃进行区域互补。我们的初步数据表明，这种基于亲核试剂的区域控制策略也可以应用于使用手性高价碘催化的不对称过程。
• PIGMENT COMPOSITION, PRODUCTION METHOD THEREFOR, AND WATER-BASED INK COMPOSITION
  申请人：FUJIFILM Corporation

  公开号：EP3677647A1

  公开（公告）日：2020-07-08

  A pigment composition including at least one pigment selected from the group consisting of a perinone-based pigment and a perylene-based pigment, water, a resin having a constitutional unit represented by Formula 1, and at least one compound selected from the group consisting of a phthalimide compound having a carboxyalkyl group and a naphthalimide compound having a carboxyalkyl group; a method for producing thereof; and an aqueous ink composition using the pigment composition. In Formula 1, R1 represents a hydrogen atom or a methyl group, L2 represents -C(=O)O-, -OC(=O)-, or -C(=O)NR2- and R2 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and R3 represents an alkyl group having 6 or more carbon atoms.

  一种颜料组合物，包括至少一种选自由过树脂基颜料和过烯基颜料组成的组的颜料、水、具有由式 1 表示的组成单元的树脂和至少一种选自由具有羧基烷基的邻苯二甲酰亚胺化合物和具有羧基烷基的萘二甲酰亚胺化合物组成的组的化合物；其生产方法；以及使用该颜料组合物的水性油墨组合物。在式1中，R1代表氢原子或甲基，L2代表-C(＝O)O-、-OC(＝O)-或-C(＝O)NR2-，R2代表氢原子或具有1至6个碳原子的烷基，R3代表具有6个或更多碳原子的烷基。
• MAZZOCCHI, P. H.;WILSON, P.;KHACHIK, F.;KLINGLER, L.;MINAMIKAWA, S., J. ORG. CHEM., 1983, 48, N 18, 2981-2989
  作者：MAZZOCCHI, P. H.、WILSON, P.、KHACHIK, F.、KLINGLER, L.、MINAMIKAWA, S.

  DOI：——

  日期：——