N-(2'-cyanoprop-2'-enyl)acetamide | 351029-29-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-(2'-cyanoprop-2'-enyl)acetamide
• 英文别名: N-(2-cyano-allyl)-acetamide；2-(Acetylamino-methyl)-acrylonitril；N-(2-Cyan-allyl)-acetamid；N-(2-cyanoallyl)acetamide；N-(2-cyanoprop-2-enyl)acetamide
• CAS: 351029-29-3
• 化学式: C₆H₈N₂O
• mdl: MFCD19217830
• 分子量: 124.142
• InChiKey: YWKIEURRMMGIMW-UHFFFAOYSA-N

物化性质

• 沸点：
  120-123 °C(Press: 0.5 Torr)
• 密度：
  1.019±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.333
• 拓扑面积：
  52.9
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(2'-cyanoprop-2'-enyl)acetamide 在 盐酸 作用下， 生成 2-(aminomethyl)acrylonitrile
  参考文献：
  名称：

  Alpha-ureidomethyl acrylonitriles and polymers thereof

  摘要：

  公开号：

  US02704751A1
• 作为产物：
  描述：

  N-(2-丙炔基)乙酰胺 生成 N-(2'-cyanoprop-2'-enyl)acetamide
  参考文献：
  名称：

  JACKSON, W. ROY;PERIMUTTER, PATRICK;SMALLRIDGE, ANDREW J., AUSTRAL. J. CHEM., 41,(1988) N, C. 1201-1208

  摘要：

  DOI：

文献信息

• A new enantioselective synthesis of β-amino acids
  作者：Dilek Saylik、Eva M. Campi、Andrew C. Donohue、W.Roy Jackson、Andrea J. Robinson

  DOI：10.1016/s0957-4166(01)00097-0

  日期：2001.3

  Enantioselective hydrogenation of some alpha,beta -unsaturated nitriles and their corresponding methyl esters bearing a phthalimidomethyl substituent at the alpha -carbon using Rh-DuPHOS catalysts afforded beta -amino acid precursors with modest e.e.s of up to 48%. Hydrogenation of the alpha,beta -unsaturated methyl esters using a Ru-BINAP catalyst gave higher e.e.s of up to 84%. Method development for the determination of the enantiomeric excesses of these derivatives using chiral HPLC is also reported. (C) 2001 Elsevier Science Ltd. All rights reserved.
• Alpha-acylaminomethyl acrylonitriles and polymers thereof
  申请人：EASTMAN KODAK CO

  公开号：US02659715A1

  公开（公告）日：1953-11-17
• Alpha-fluoroacylaminomethyl acrylonitriles and polymers thereof
  申请人：EASTMAN KODAK CO

  公开号：US02706728A1

  公开（公告）日：1955-04-19
• US4931100A
  申请人：——

  公开号：US4931100A

  公开（公告）日：1990-06-05
• [EN] INORGANIC FINE PARTICLE DISPERSION, ORGANIC-INORGANIC HYBRID COMPOSITION, SHAPED ARTICLE AND OPTICAL COMPONENT<br/>[FR] DISPERSION DE PARTICULES INORGANIQUES FINES, COMPOSITION HYBRIDE ORGANIQUE-INORGANIQUE, ARTICLE FAÇONNÉ ET COMPOSANT OPTIQUE
  申请人：FUJIFILM CORP

  公开号：WO2009151143A1

  公开（公告）日：2009-12-17

  An inorganic fine particle dispersion comprising inorganic fine particles having a particle size of from 1 to 15 nm in a concentration of from 1 to 70% by mass, a chlorine element in a concentration of at most 100 ppm, and at least one of an organic acid and an inorganic acid, wherein the total concentration of the organic acid and the inorganic acid is less than 0.15 times the solid concentration of the inorganic fine particles, is capable of keeping its high transparency even when mixed with a thermoplastic resin to give an organic-inorganic hybrid composition.