p-xylyleneglycol-bis-(pentachlorophenyl) ether | 57267-84-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: p-xylyleneglycol-bis-(pentachlorophenyl) ether
• 英文别名: 1,2,3,4,5-Pentachloro-6-[[4-[(2,3,4,5,6-pentachlorophenoxy)methyl]phenyl]methoxy]benzene；1,2,3,4,5-pentachloro-6-[[4-[(2,3,4,5,6-pentachlorophenoxy)methyl]phenyl]methoxy]benzene
• CAS: 57267-84-2
• 化学式: C₂₀H₈Cl₁₀O₂
• 分子量: 634.812
• InChiKey: MSLIHTUMPACZAP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  32
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  pentachlorophenol sodium 、 1,4-对二氯苄 以 乙二醇甲醚 为溶剂， 以811 g (85%)的产率得到p-xylyleneglycol-bis-(pentachlorophenyl) ether
  参考文献：
  名称：

  Method of preparing polynuclear, halogenated, aromatic benzyl ethers

  摘要：

  一种芳香性多核卤代芳基醚，化学式为##STR1## 其中W是氯或溴原子或甲基基团或基团--CH.sub.2.Z，所述基团W相对于CH.sub.2.Z基团呈正交、间位或对位排列，Hal代表氯或溴原子，n为0至4，Z代表通式##STR2## 中的苯氧基团，其中X是氯或溴原子，R是氢原子或具有1至4个碳原子的烷基基团，a为2至5，b为(5-i a)；一种通过将通式##STR3## 中的苄卤与之前指定的含义的Hal和n接触，其中X是氯或溴原子，Y与CH.sub.2 X相同或是氢或氯原子或甲基基团，且相对于基团--CH.sub.2 X呈正交、间位或对位排列，以及一种卤代酚的苯酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚

  公开号：

  US04039587A1

文献信息

• US4039587A
  申请人：——

  公开号：US4039587A

  公开（公告）日：1977-08-02
• Method of preparing polynuclear, halogenated, aromatic benzyl ethers
  申请人：Dynamit Nobel Aktiengesellschaft

  公开号：US04039587A1

  公开（公告）日：1977-08-02

  An aromatic polynuclear, halogenated, aromatic benzyl ether of the formula ##STR1## WHEREIN W is a chlorine or bromine atom or a methyl radical or the radical --CH.sub.2.Z, said radical W being disposed in the ortho, meta or para position with respect to the CH.sub.2.Z radical, Hal represents a chlorine or bromine atom, n is 0 to 4 and Z represents a phenoxy radical of the general formula ##STR2## wherein X is a chlorine or bromine atom, R is a hydrogen atom or an alkyl radical having 1 to 4 carbon atoms, a is 2 to 5 and b is (5-i a); a process for producing such polynuclear halogenated benzyl ether by contacting a benzyl halide of the general formula ##STR3## wherein Hal and n have the previously assigned significance, X is a chlorine or bromine atom, Y is the same as CH.sub.2 X or is a hydrogen or chlorine atom or a methyl radical and is disposed in the ortho, meta or para position with respect to the radical --CH.sub.2 X, and a phenolate of a halogen phenol which halogen phenol has the formula ##STR4## WHEREIN X, R, a and b have the previously assigned significance, in a glycol monoalkyl ether reaction medium until the ether is formed and thereafter isolating the ether.

  一种芳香性多核卤代芳基醚，化学式为##STR1## 其中W是氯或溴原子或甲基基团或基团--CH.sub.2.Z，所述基团W相对于CH.sub.2.Z基团呈正交、间位或对位排列，Hal代表氯或溴原子，n为0至4，Z代表通式##STR2## 中的苯氧基团，其中X是氯或溴原子，R是氢原子或具有1至4个碳原子的烷基基团，a为2至5，b为(5-i a)；一种通过将通式##STR3## 中的苄卤与之前指定的含义的Hal和n接触，其中X是氯或溴原子，Y与CH.sub.2 X相同或是氢或氯原子或甲基基团，且相对于基团--CH.sub.2 X呈正交、间位或对位排列，以及一种卤代酚的苯酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚酚